RPSII

Re-wiring of photosystem II enzymes to metal-oxide electrodes in artificial photosynthetic devices for enhanced photocatalytic water splitting performance

Coordinatore	THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE    more  Organization address address: The Old Schools, Trinity Lane city: CAMBRIDGE postcode: CB2 1TN contact info Titolo: Ms. Nome: Renata Cognome: Schaeffer Email: send email Telefono: +44 1223 333543 Fax: +44 1223 332988
Nazionalità Coordinatore	United Kingdom [UK]
Totale costo	221˙606 €
EC contributo	221˙606 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2012-IIF
Funding Scheme	MC-IIF
Anno di inizio	2013
Periodo (anno-mese-giorno)	2013-03-11   -   2015-03-10

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE  Organization address address: The Old Schools, Trinity Lane city: CAMBRIDGE postcode: CB2 1TN contact info Titolo: Ms. Nome: Renata Cognome: Schaeffer Email: send email Telefono: +44 1223 333543 Fax: +44 1223 332988	UK (CAMBRIDGE)	coordinator	221˙606.40

Mappa

 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

 Obiettivo del progetto (Objective)

'Photocatalytic water splitting is an attractive means of efficiently converting solar energy into a storable hydrogen fuel, offering a clean and renewable source of energy that can replace fossil fuel. In this study, the Photosystem II (PSII) enzyme is employed as a biological catalyst in important proof-of-principle studies to establish the basic principles behind emerging artificial photosynthetic devices for efficient light-driven water splitting. Currently, the maximal output of PSII-based photocatalytic water splitting systems is capped by a number of factors, most significantly the non-ideal ‘wiring’ of the enzymes to the electrode giving rise to inefficient electron transfer. The present Marie Curie International Incoming Fellowship (IIF) project proposes to enhance the performance of benchmark PSII-based photocatalytic systems by ‘rewiring’ the electron transfer from the bio-catalyst to the anode to eliminate inefficient steps, and hence establish new maximal outputs achievable by such systems. This will be achieved by directed immobilisation of the PSII to the anode, followed by the inhibition of redox events in the electron flow pathway to bypass the rate-limiting step. Moreover, current photocatatlyic water splitting systems rely on expensive rare-earth components which are ultimately non-sustainable and uneconomical for use in future photocatalytic devices. In this study, newly accessible nano-structured earth-abundant substrates will be investigated as electrode material to ultimately encourage the development of more sustainable systems for photocatalytic water splitting.'