SMARTMIP

Modulated Catalysis by Smart Molecularly Imprinted Polymers

 Coordinatore CRANFIELD UNIVERSITY 

 Organization address address: College Road
city: CRANFIELD - BEDFORDSHIRE
postcode: MK43 0AL

contact info
Titolo: Prof.
Nome: Anthony
Cognome: Turner
Email: send email
Telefono: +44 (0)1234 758355
Fax: + 44(0) 1234 758380

 Nazionalità Coordinatore United Kingdom [UK]
 Totale costo 0 €
 EC contributo 181˙350 €
 Programma FP7-PEOPLE
Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call FP7-PEOPLE-IIF-2008
 Funding Scheme MC-IIF
 Anno di inizio 2009
 Periodo (anno-mese-giorno) 2009-12-08   -   2011-12-07

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    CRANFIELD UNIVERSITY

 Organization address address: College Road
city: CRANFIELD - BEDFORDSHIRE
postcode: MK43 0AL

contact info
Titolo: Prof.
Nome: Anthony
Cognome: Turner
Email: send email
Telefono: +44 (0)1234 758355
Fax: + 44(0) 1234 758380

UK (CRANFIELD - BEDFORDSHIRE) coordinator 181˙350.77

Mappa


 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

water    imprinting    molecular    transition    accessible    binding    substrates    opening    smart    tunable    prepared    catalysis    polymers    framework   

 Obiettivo del progetto (Objective)

'Molecular imprinting, an important methodology for the straightforward prepared of antibody-like polymers, is recently one of focuses in chemistry because of its importance in catalysis, separation and sensing. Described usually as a ‘from-key-to-lock’ process, the molecular imprinting recognizes and interacts with substrates basing on a specifically complementary framework. The present proposal aims to design ‘smart’ imprinted polymers capable of showing tunable catalysis. Inspired by recent advances in the ‘Smart’ technology, a unique hydrophilic/hydrophobic transition is created within the binding framework. The design of this transition will cause an opening/closing-tunable mechanism within the binding framework, thereby allowing/refusing the substrates in water accessible to the interior. In the opening state, the substrate in water can be freely accessible to the binding framework, thus making possible efficient interaction. Above the transition the blockage of access to the inner largely restricts the diffusion of substrates. In this way, such recognition and catalysis are comparable to an on/off-switchable process, which thus allows one to manipulate the activity by controlling the phase behaviours of prepared materials.'

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