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SPICY

Silicon and polyanionic chemistries and architectures of Li-ion cell for high energy battery

Total Cost €

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EC-Contrib. €

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Partnership

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Project "SPICY" data sheet

The following table provides information about the project.

Coordinator
COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES 

Organization address
address: RUE LEBLANC 25
city: PARIS 15
postcode: 75015
website: www.cea.fr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country France [FR]
 Project website http://www.spicy-project.eu
 Total cost 7˙250˙428 €
 EC max contribution 6˙896˙053 € (95%)
 Programme 1. H2020-EU.3.4. (SOCIETAL CHALLENGES - Smart, Green And Integrated Transport)
 Code Call H2020-GV-2014
 Funding Scheme RIA
 Starting year 2015
 Duration (year-month-day) from 2015-05-01   to  2018-07-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES FR (PARIS 15) coordinator 1˙590˙079.00
2    TECHNISCHE UNIVERSITAET MUENCHEN DE (MUENCHEN) participant 982˙453.00
3    FUNDACION CIDETEC ES (SAN SEBASTIAN) participant 847˙522.00
4    VLAAMSE INSTELLING VOOR TECHNOLOGISCH ONDERZOEK N.V. BE (MOL) participant 726˙062.00
5    PRAYON S.A BE (Engis) participant 619˙753.00
6    KARLSRUHER INSTITUT FUER TECHNOLOGIE DE (KARLSRUHE) participant 507˙348.00
7    CENTRE TECHNIQUE INDUSTRIEL DE LA PLASTURGIE ET DES COMPOSITES FR (BELLIGNAT) participant 339˙611.00
8    HAHN-SCHICKARD-GESELLSCHAFT FUER ANGEWANDTE FORSCHUNG E.v. DE (Villingen) participant 337˙250.00
9    TEKNA PLASMA EUROPE FR (MACON) participant 311˙750.00
10    FORSCHUNGSZENTRUM JULICH GMBH DE (JULICH) participant 254˙723.00
11    WAVESTONE LUXEMBOURG SA LU (LEUDELANGE) participant 214˙687.00
12    RECUPYL SAS FR (DOMENE) participant 141˙569.00
13    PROLLION SAS FR (SAINT MARTIN D HERES CEDEX) participant 23˙241.00
14    BELIFE BE (ENGIS) participant 0.00
15    EIDGENOSSISCHE MATERIALPRUFUNGS- UND FORSCHUNGSANSTALT CH (DUBENDORF) participant 0.00

Map

 Project objective

SPICY is a collaborative research project associating 5 industrials partners (3 large groups and 2 SME) with 8 academic and research centres to the multidisciplinary development of a new generation of Li-ion batteries meeting the expectations of electrical vehicle end-users, including performances, safety, cost, recyclability and lifetime. For this purpose, SPICY will consider the development of new chemistry materials, cell architectures and packaging with the support of understanding and modelling activities. SPICY will address the whole value chain until the implementation of manufacturing. SPICY will focus on polyanionic phosphates for the cathode material. LiFePO4 is well known as a safer and more durable cathode material. Unfortunately, its energy density is low due to the electrochemical potential of Fe. One objective of SPICY will be to bind metals having a higher potential than Fe, allowing an increase of the material potential, and thus a higher energy. Regarding the anode material, SPICY will study two chemistries. Graphite is used in current Li-ion cells and remains one of the major anode materials for the next generation of Li-ion cells. Silicon is appropriate for high energy cell applications but has lower cyclability. Silicon will be investigated through new synthesis process methods providing nanoparticles and core-shell structures to improve particle stability. Active and passive components will be harmonized for a higher energy density i.e: polyanionic phosphate /graphite up to 200 Wh/kg, and polyanionic/Si up to 230 Wh/kg. In addition, three cells architectures and packaging will be investigated. The thermal behaviour of these cells will be studied in ageing tests in order to model Li-ion cells. Finally, the industrial environment will be considered and SPICY solution will be assessed so as to optimise cost and to integrate eco-design, thereby supporting the future development of a strong industrial base in this field.

 Deliverables

List of deliverables.
New packaging for Li-ion cell: tools and process definition Documents, reports 2019-05-31 11:41:08
Input document for standards related to Li-ion batteries Websites, patent fillings, videos etc. 2019-05-31 11:41:16
Test protocols definition for WP6 (including critical review of protocols) Documents, reports 2019-05-31 12:01:25
Announcement about the manufacturing of cells Other 2019-05-31 12:01:07
Communication tools (project identity set, website) Websites, patent fillings, videos etc. 2019-05-31 12:01:15
Post-mortem analysis protocols Documents, reports 2019-05-31 12:01:25
State of the art of Current Recycling processes and compatibility with the new lithium ion battery Documents, reports 2019-05-31 12:01:13

Take a look to the deliverables list in detail:  detailed list of SPICY deliverables.

 Publications

year authors and title journal last update
List of publications.
2017 Leparoux, M
Inductively coupled thermal plasma – A versatile tool for the processing of powders
published pages: , ISSN: , DOI:
5th International Conference on PLASMA CHEMISTRY AND PLASMA PROCESSING 2019-05-29
2018 Katharina Rumpf, Alexander Rheinfeld, Markus Schindler, Jonas Keil, Tobias Schua, Andreas Jossen
Influence of Cell-to-Cell Variations on the Inhomogeneity of Lithium-Ion Battery Modules
published pages: A2587-A2607, ISSN: 0013-4651, DOI: 10.1149/2.0111811jes
Journal of The Electrochemical Society 165/11 2019-05-29
2017 Antaryami Mohanta, Briac Lanfant, Mehari Asfaha, Marc Leparoux
Optical emission spectroscopic study of Ar/H 2 /CH 4 plasma during the production of graphene nano-flakes by induction plasma synthesis
published pages: 12010, ISSN: 1742-6588, DOI: 10.1088/1742-6596/825/1/012010
Journal of Physics: Conference Series 825 2019-05-29
2017 Antaryami Mohanta, Briac Lanfant, Mehari Asfaha, Marc Leparoux
Methane dissociation process in inductively coupled Ar/H 2 /CH 4 plasma for graphene nano-flakes production
published pages: 93109, ISSN: 0003-6951, DOI: 10.1063/1.4977568
Applied Physics Letters 110/9 2019-05-29
2018 Stéphane Dessors , Maximilian Barth, Thomas Meißner, Yan Lopez, Come Leys, Yvan Reynier, Willy Porcher, Lionel Tenchine
A new packaging solution for Li-ion battery cells
published pages: , ISSN: , DOI:
Proceedings of the 7th Transport Research Arena 2019-04-03
2018 Niloofar Ehteshami, Aitor Eguia-Barrio, Iratxe de Meatza, Willy Porcher, Elie Paillard
Adiponitrile-based electrolytes for high voltage, graphite-based Li-ion battery
published pages: 52-58, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2018.07.004
Journal of Power Sources 397 2019-04-03
2018 W. Porcher, J.-B. Ducros, C. Haon, G. Claude, M. Montaru, T. Zhang, N. Ehteshami, E. Paillard, D. Eskenazi, M. Oyarbide, I. de Meatza, G. Mulder, T. Khiem, S. Kosch, D. Vieira Carvalho, A. Moretti, S. Passerini
Silicon and polyanionic chemistries and architectures of Li-ion cell for high energy battery
published pages: , ISSN: , DOI:
TRA 2018 – Transport Research Arena 2019-04-03
2018 I. de Meatza, M. Bengoechea, A. Eguía-Barrio, F. Tedjar , J. Cognard , D. Vieira Carvalho, A. Moretti, S. Passerini
Enhancing lithium-ion battery recycling: evaluation of graphite and carbon recovered from aged cells for the production of “new” negative electrodes
published pages: , ISSN: , DOI:
TRA 2018 – Transport Research Arena 2019-04-03
2018 Dominic Bresser, Daniel Buchholz, Arianna Moretti, Alberto Varzi and Stefano Passerini
Alternative binders for sustainable electrochemical energy storage – the transition to aqueous electrode processing and bio-derived polymers
published pages: , ISSN: 1754-5706, DOI:
Energy and Environmental Science 2019-05-29
2018 Tong Zhang, Willy Porcher, Elie Paillard
Towards practical sulfolane based electrolytes: Choice of Li salt for graphite electrode operation
published pages: 212-220, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2018.05.077
Journal of Power Sources 395 2019-05-29
2017 Jan-Philipp Hoffknecht, Mathias Drews, Xin He, Elie Paillard
Investigation of the N -butyl- N -methyl pyrrolidinium trifluoromethanesulfonyl- N -cyanoamide (PYR 14 TFSAM) ionic liquid as electrolyte for Li-ion battery
published pages: 25-34, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2017.08.020
Electrochimica Acta 250 2019-05-29
2018 Stephan Kosch, Yulong Zhao, Johannes Sturm, Jörg Schuster, Grietus Mulder, Elixabete Ayerbe, Andreas Jossen
A Computationally Efficient Multi-Scale Model for Lithium-Ion Cells
published pages: A2374-A2388, ISSN: 0013-4651, DOI: 10.1149/2.1241810jes
Journal of The Electrochemical Society 165/10 2019-05-29
2017 Tong Zhang, Iratxe de Meatza, Xin Qi, Elie Paillard
Enabling steady graphite anode cycling with high voltage, additive-free, sulfolane-based electrolyte: Role of the binder
published pages: 97-102, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2017.04.073
Journal of Power Sources 356 2019-04-03
2018 Sharova, Varvara
Enhancing the performance of lithium batteries through the development of improved electrolyte formulation, formation protocol and graphite surface modification
published pages: , ISSN: , DOI: 10.5445/IR/1000079331
2019-05-29

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