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TM-FLPS TERMINATED

Bond Activation and Catalysis by Transition Metal Frustrated Lewis Pairs

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

TM-FLPS project word cloud

Explore the words cloud of the TM-FLPS project. It provides you a very rough idea of what is the project "TM-FLPS" about.

homogenous unexplored reactivity ultimately relevance contrasts enormous host unreachable substituting ultimate literature la critical stage catalysis subsequently manufacture abundant diversity limited acid metal pairs sustainability variety activation bn bond possibilities elementary generating founding combine decade young au extraordinary usefulness principles catalysts preliminary chemicals ecologically transition homogeneous approaching explored ca give attributes advantages world context first components expansion ago manufacturing discoveries cycles catalytic ing 75 lewis unlimited reactions flp powerful base metals flps avenues confidence chemistry mainly frustrated industrial group place perspective rapid pt extend expand hydrogenation centres earth benign row examples structural

Project "TM-FLPS" data sheet

The following table provides information about the project.

Coordinator	UNIVERSIDAD DE SEVILLA Organization address address: CALLE S. FERNANDO 4 city: SEVILLA postcode: 41004 website: www.us.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Project website	http://www.us.es
Total cost	170˙121 €
EC max contribution	170˙121 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-ST
Starting year	2016
Duration (year-month-day)	from 2016-10-01 to 2018-09-30

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSIDAD DE SEVILLA UNIVERSIDAD DE SEVILLA Organization address address: CALLE S. FERNANDO 4 city: SEVILLA postcode: 41004 website: www.us.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (SEVILLA)	coordinator	170˙121.00

Map

Project objective

Catalysis is critical to the delivery of future growth in the manufacturing sector: ca. 75% of all chemicals currently require catalysts at some stage in their manufacture, with catalytic processes generating €1,000 Bn in products world-wide. This proposal targets a step-change in homogenous catalysis by approaching it from a new perspective. Frustrated Lewis Pairs (FLPs) are among the most promising new avenues for the development of future catalysts and offer important advantages in the context of sustainability. Thus the young field of FLP chemistry has experienced an enormous expansion since its founding discoveries one decade ago. However, this rapid development contrasts with the very limited number of examples in the literature in which one of the Lewis acid/base (LA/B) components is based on a transition metal. The current proposal aims to combine the rich chemistry of transition metals (ultimately Earth-abundant elements) with the powerful reactivity offered by FLP systems by substituting one of its LA/B components by a transition metal. The extraordinary structural diversity of transition metals, along with the rich variety of elementary reactions that take place over those centres, are attributes that will extend the usefulness of FLPs far beyond the present (mainly) hydrogenation reactions and should allow developing new catalytic processes unreachable for current homogeneous catalysts. The possibilities are as unexplored as unlimited. We aim to exploit Pt and Au systems, for which preliminary results are available in the host group and will give high confidence of short-term success. Subsequently we will build on the key principles so established to expand our approach to ecologically more benign first-row transition metals. The potential in bond activation and catalysis of the resulting transition metal FLP systems will be explored with the ultimate goal of developing novel catalytic cycles of industrial relevance.

Publications

List of publications.
year	authors and title	journal	last update
2017	J. Campos Pares de Lewis Frustrados basados en Metales de TransiciÃ³n published pages: , ISSN: 1575-3417, DOI:	Anales de Quimica	2019-06-13
2017	JesÃºs Campos Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair published pages: 2944-2947, ISSN: 0002-7863, DOI: 10.1021/jacs.7b00491	Journal of the American Chemical Society 139/8	2019-06-13

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