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TM-FLPS TERMINATED

Bond Activation and Catalysis by Transition Metal Frustrated Lewis Pairs

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 TM-FLPS project word cloud

Explore the words cloud of the TM-FLPS project. It provides you a very rough idea of what is the project "TM-FLPS" about.

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Project "TM-FLPS" data sheet

The following table provides information about the project.

Coordinator
UNIVERSIDAD DE SEVILLA 

Organization address
address: CALLE S. FERNANDO 4
city: SEVILLA
postcode: 41004
website: www.us.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Project website http://www.us.es
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2016
 Duration (year-month-day) from 2016-10-01   to  2018-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSIDAD DE SEVILLA ES (SEVILLA) coordinator 170˙121.00

Map

 Project objective

Catalysis is critical to the delivery of future growth in the manufacturing sector: ca. 75% of all chemicals currently require catalysts at some stage in their manufacture, with catalytic processes generating €1,000 Bn in products world-wide. This proposal targets a step-change in homogenous catalysis by approaching it from a new perspective. Frustrated Lewis Pairs (FLPs) are among the most promising new avenues for the development of future catalysts and offer important advantages in the context of sustainability. Thus the young field of FLP chemistry has experienced an enormous expansion since its founding discoveries one decade ago. However, this rapid development contrasts with the very limited number of examples in the literature in which one of the Lewis acid/base (LA/B) components is based on a transition metal. The current proposal aims to combine the rich chemistry of transition metals (ultimately Earth-abundant elements) with the powerful reactivity offered by FLP systems by substituting one of its LA/B components by a transition metal. The extraordinary structural diversity of transition metals, along with the rich variety of elementary reactions that take place over those centres, are attributes that will extend the usefulness of FLPs far beyond the present (mainly) hydrogenation reactions and should allow developing new catalytic processes unreachable for current homogeneous catalysts. The possibilities are as unexplored as unlimited. We aim to exploit Pt and Au systems, for which preliminary results are available in the host group and will give high confidence of short-term success. Subsequently we will build on the key principles so established to expand our approach to ecologically more benign first-row transition metals. The potential in bond activation and catalysis of the resulting transition metal FLP systems will be explored with the ultimate goal of developing novel catalytic cycles of industrial relevance.

 Publications

year authors and title journal last update
List of publications.
2017 J. Campos
Pares de Lewis Frustrados basados en Metales de Transición
published pages: , ISSN: 1575-3417, DOI:
Anales de Quimica 2019-06-13
2017 Jesús Campos
Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair
published pages: 2944-2947, ISSN: 0002-7863, DOI: 10.1021/jacs.7b00491
Journal of the American Chemical Society 139/8 2019-06-13

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