NanoSiAl
Silica and alumina nanophases – the building blocks for the ground under our feet.
Total Cost €
0EC-Contrib. €
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Project "NanoSiAl" data sheet
The following table provides information about the project.
| Coordinator |
HELMHOLTZ ZENTRUM POTSDAM DEUTSCHESGEOFORSCHUNGSZENTRUM GFZ
Organization address contact info |
| Coordinator Country | Germany [DE] |
| Project website | https://github.com/tomaszstawski/SilicaLysozymeSAXS |
| Total cost | 171˙460 € |
| EC max contribution | 171˙460 € (100%) |
| Programme |
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility) |
| Code Call | H2020-MSCA-IF-2015 |
| Funding Scheme | MSCA-IF-EF-ST |
| Starting year | 2017 |
| Duration (year-month-day) | from 2017-05-01 to 2019-10-30 |
Partnership
Take a look of project's partnership.
| # | ||||
|---|---|---|---|---|
| 1 | HELMHOLTZ ZENTRUM POTSDAM DEUTSCHESGEOFORSCHUNGSZENTRUM GFZ | DE (POTSDAM) | coordinator | 171˙460.00 |
Map
Project objective
Alumina and silica nanophases play a crucial role in rock weathering and their formation and destruction controls Earth’s response to global climate change. The presence of various products of aqueous weathering of aluminosilicates points to a complex activity of water, and is considered as the geological indication for the occurrence of life-habitable conditions. In this regard, a more complete picture of the water-alumina-silica interactions would allow for better specifying the molecular-level conditions for early life. Upon weathering the original Al- and Si-containing phases are dissolved at the solid-water interface, undergo hydrolysis and condensation reactions and form new colloidal nanoparticles. However, quantitative and mechanistic understanding of the underlying processes that lead to the formation and types of Al and Si phases is still lacking, due to the insufficient in situ methodology providing structural information about the colloidal species in solution.
Therefore, the main objective of the NanoSiAl project is to develop, test and validate the methods for the direct in situ and real-time structural and kinetic characterisation of the alumina and silica colloid formation pathways at the length-scale of < 100 nm. I will achieve this by utilising state-of-the-art in situ liquid-cell transmission electron microscopy (L-C TEM) complemented with synchrotron-based scattering methods. This way I will be able to fully avoid the usual artefacts of sample varying and hard-vacuum conditions, because the L-C TEM and scattering methods allow for direct in situ characterisation of nano-sized objects in solution with a near-atomic-resolution. This combination of novel techniques will provide unprecedented insights on properties of the molecular building blocks for alumina and silica as they nucleate, grow and assembly with each other.
Publications
| year | authors and title | journal | last update |
|---|---|---|---|
| 2019 |
Tomasz M. Stawski, Helen M. Freeman, Alexander E. S. Van Driessche, Jörn Hövelmann, Rogier Besselink, Richard Wirth, Liane G. Benning Particle-Mediated Nucleation Pathways Are Imprinted in the Internal Structure of Calcium Sulfate Single Crystals published pages: 3714-3721, ISSN: 1528-7483, DOI: 10.1021/acs.cgd.9b00066 |
Crystal Growth & Design 19/7 | 2020-03-20 |
| 2017 |
Mercedes Ossorio, Tomasz Stawski, Juan RodrÃguez-Blanco, Mike Sleutel, Juan GarcÃa-Ruiz, Liane Benning, Alexander Van Driessche Physicochemical and Additive Controls on the Multistep Precipitation Pathway of Gypsum published pages: 140, ISSN: 2075-163X, DOI: 10.3390/min7080140 |
Minerals 7/8 | 2020-03-20 |
| 2019 |
Jörn Hövelmann, Tomasz M. Stawski, Rogier Besselink, Helen M. Freeman, Karen M. Dietmann, Sathish Mayanna, Brian R. Pauw, Liane G. Benning A template-free and low temperature method for the synthesis of mesoporous magnesium phosphate with uniform pore structure and high surface area published pages: 6939-6951, ISSN: 2040-3364, DOI: 10.1039/c8nr09205b |
Nanoscale 11/14 | 2020-03-20 |
| 2018 |
Adriana Matamoros-Veloza, Tomasz M. Stawski, Liane G. Benning Nanoparticle Assembly Leads to Mackinawite Formation published pages: 6757-6764, ISSN: 1528-7483, DOI: 10.1021/acs.cgd.8b01025 |
Crystal Growth & Design 18/11 | 2020-03-20 |
| 2018 |
Daniela B. van den Heuvel, Tomasz M. Stawski, Dominique J. Tobler, Richard Wirth, Caroline L. Peacock, Liane G. Benning Formation of Silica-Lysozyme Composites Through Co-Precipitation and Adsorption published pages: , ISSN: 2296-8016, DOI: 10.3389/fmats.2018.00019 |
Frontiers in Materials 5 | 2020-03-20 |
| 2017 |
R. Besselink, J. D. Rodriguez-Blanco, T. M. Stawski, L. G. Benning, D. J. Tobler How Short-Lived Ikaite Affects Calcite Crystallization published pages: 6224-6230, ISSN: 1528-7483, DOI: 10.1021/acs.cgd.7b00743 |
Crystal Growth & Design 17/12 | 2020-03-20 |
| 2019 |
Tomasz M. Stawski, Alexander E. S. Van Driessche, Rogier Besselink, Emily H. Byrne, Paolo Raiteri, Julian D. Gale, Liane G. Benning The Structure of CaSO 4 Nanorods: The Precursor of Gypsum published pages: 23151-23158, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.9b04268 |
The Journal of Physical Chemistry C 123/37 | 2020-03-20 |
| 2019 |
A.E.S. Van Driessche, T.M. Stawski, M. Kellermeier Calcium sulfate precipitation pathways in natural and engineering environments published pages: 119274, ISSN: 0009-2541, DOI: 10.1016/j.chemgeo.2019.119274 |
Chemical Geology | 2020-03-20 |
| 2019 |
Jörn Hövelmann, Tomasz M. Stawski, Helen M. Freeman, Rogier Besselink, Sathish Mayanna, Jeffrey Paulo H. Perez, Nicole S. Hondow, Liane G. Benning Struvite Crystallisation and the Effect of Co2+ Ions published pages: 503, ISSN: 2075-163X, DOI: 10.3390/min9090503 |
Minerals 9/9 | 2020-03-20 |
| 2019 |
Tomasz M Stawski, Daniela B van den Heuvel, Rogier Besselink, Dominique J Tobler, Liane G Benning Mechanism of silica–lysozyme composite formation unravelled by in situ fast SAXS published pages: 182-197, ISSN: 2190-4286, DOI: 10.3762/bjnano.10.17 |
Beilstein Journal of Nanotechnology 10 | 2020-03-20 |
| 2018 |
Daniela B. van den Heuvel, Einar Gunnlaugsson, Ingvi Gunnarsson, Tomasz M. Stawski, Caroline L. Peacock, Liane G. Benning Understanding amorphous silica scaling under well-constrained conditions inside geothermal pipelines published pages: 231-241, ISSN: 0375-6505, DOI: 10.1016/j.geothermics.2018.07.006 |
Geothermics 76 | 2020-03-20 |
| 2018 |
Tomasz M. Stawski, Teresa Roncal-Herrero, Alejandro Fernandez-Martinez, Adriana Matamoros-Veloza, Roland Kröger, Liane G. Benning “On demand†triggered crystallization of CaCO 3 from solute precursor species stabilized by the water-in-oil microemulsion published pages: 13825-13835, ISSN: 1463-9076, DOI: 10.1039/C8CP00540K |
Physical Chemistry Chemical Physics 20/20 | 2020-03-20 |
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