Explore the words cloud of the ILID project. It provides you a very rough idea of what is the project "ILID" about.
The following table provides information about the project.
FRIEDRICH-ALEXANDER-UNIVERSITAET ERLANGEN NUERNBERG
|Coordinator Country||Germany [DE]|
|Total cost||2˙498˙125 €|
|EC max contribution||2˙498˙125 € (100%)|
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
|Duration (year-month-day)||from 2016-10-01 to 2021-09-30|
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|1||FRIEDRICH-ALEXANDER-UNIVERSITAET ERLANGEN NUERNBERG||DE (ERLANGEN)||coordinator||2˙498˙125.00|
The aim of the project is to take the ground-breaking step from our present knowledge of static properties to the understanding and control of dynamical processes at ionic liquid interfaces. Ionic liquids (ILs) are chosen as model systems for liquids in general for two reasons: First, their structural diversity allows their properties to be tailored over a wide range, and second, they can be studied using the extremely powerful methods of surface science in ultra-high vacuum due to their low vapor pressure. Such studies cannot be performed for conventional liquids, since they evaporate. ILs are not only relevant from a fundamental point of view, but also for a variety of applications. In catalysis, two new concepts have been put forward: Supported Ionic Liquid Phase (SILP) and Solid Catalyst with Ionic Liquid Layer (SCILL). In both, a high surface area solid substrate is covered with a thin IL film, which contains a dissolved metal complex for SILP, or which modifies active sites at the support for SCILL. For these and other applications, a fundamental understanding of the dynamical processes at the gas/IL and/or IL/support interfaces is strongly needed, but does not exist. Equally important, but even more challenging, is the investigation of the dynamics of chemical reactions in ILs, also under electrochemical conditions. Therefore, the applicant proposes a multi-method approach with new and unique setups to follow these dynamical processes in real time, that is, while they occur. Towards this goal, four key topics will be addressed: (A) How do gases pass through the gas/liquid interface? (B) How does the liquid/solid interface form? (C) Real-time studies of reactions in ILs, and (D) Real-time studies of electrochemical processes in ILs. The achieved insight will then enable to control the processes at the molecular level by tailoring the properties of the ILs. This promises a breakthrough not only for ILs, but for liquid interfaces in general.
|year||authors and title||journal||last update|
Benjamin May, Michael HÃ¶nle, Bettina Heller, Francesco Greco, Radha Bhuin, Hans-Peter SteinrÃ¼ck, Florian Maier
Surface-Induced Changes in the Thermochromic Transformation of an Ionic Liquid Cobalt Thiocyanate Complex
published pages: 1137-1141, ISSN: 1948-7185, DOI: 10.1021/acs.jpclett.7b00142
|The Journal of Physical Chemistry Letters 8/6||2019-06-14|
Karina Shimizu, Bettina S. J. Heller, Florian Maier, Hans-Peter SteinrÃ¼ck, JosÃ© N. Canongia Lopes
Probing the Surface Tension of Ionic Liquids Using the Langmuir Principle
published pages: 4408-4416, ISSN: 0743-7463, DOI: 10.1021/acs.langmuir.7b04237
Matthias Lexow, Timo Talwar, Bettina S. J. Heller, Benjamin May, Radha G. Bhuin, Florian Maier, Hans-Peter SteinrÃ¼ck
Time-dependent changes in the growth of ultrathin ionic liquid films on Ag(111)
published pages: 12929-12938, ISSN: 1463-9076, DOI: 10.1039/c8cp01411f
|Physical Chemistry Chemical Physics 20/18||2019-06-14|
F. Maier, I. Niedermaier, H.-P. SteinrÃ¼ck
Perspective: Chemical reactions in ionic liquids monitored through the gas (vacuum)/liquid interface
published pages: 170901, ISSN: 0021-9606, DOI: 10.1063/1.4982355
|The Journal of Chemical Physics 146/17||2019-06-14|
Bettina S. J. Heller, Claudia Kolbeck, Inga Niedermaier, Sabine Dommer, JÃ¼rgen Schatz, Patricia Hunt, Florian Maier, Hans-Peter SteinrÃ¼ck
Surface Enrichment in Equimolar Mixtures of Non-Functionalized and Functionalized Imidazolium-Based Ionic Liquids
published pages: 1733-1745, ISSN: 1439-4235, DOI: 10.1002/cphc.201800216
Radha G. Bhuin, Patrick Schreiber, Bettina S.J. Heller, Marlene Scheuermeyer, Peter Wasserscheid, Hans-Peter SteinrÃ¼ck, Florian Maier
Surface behavior of low-temperature molten salt mixtures during the transition from liquid to solid
published pages: 290-296, ISSN: 0167-7322, DOI: 10.1016/j.molliq.2018.11.056
|Journal of Molecular Liquids 275||2019-05-22|
Benjamin May, Matthias Lexow, Nicola Taccardi, Hans-Peter SteinrÃ¼ck, Florian Maier
Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold
published pages: 15-22, ISSN: 2191-1363, DOI: 10.1002/open.201800149
Matthias Lexow, Bettina S. J. Heller, Gabriel Partl, Radha G. Bhuin, Florian Maier, Hans-Peter SteinrÃ¼ck
Cation Exchange at the Interfaces of Ultrathin Films of Fluorous Ionic Liquids on Ag(111)
published pages: 398-405, ISSN: 0743-7463, DOI: 10.1021/acs.langmuir.8b03517
Matthias Lexow, Bettina S. J. Heller, Florian Maier, Hans-Peter SteinrÃ¼ck
Anion Exchange at the Liquid/Solid Interface of Ultrathin Ionic Liquid Films on Ag(111)
published pages: 2978-2984, ISSN: 1439-4235, DOI: 10.1002/cphc.201800773
Vicent Lloret, Miguel Ãngel Rivero-Crespo, JosÃ© Alejandro Vidal-Moya, Stefan Wild, Antonio DomÃ©nech-CarbÃ³, Bettina S. J. Heller, Sunghwan Shin, Hans-Peter SteinrÃ¼ck, Florian Maier, Frank Hauke, Maria Varela, Andreas Hirsch, Antonio Leyva-PÃ©rez, Gonzalo AbellÃ¡n
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
published pages: 509, ISSN: 2041-1723, DOI: 10.1038/s41467-018-08063-3
|Nature Communications 10/1||2019-05-15|
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