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chem-fs-MOF SIGNED

Chemical Engineering of Functional Stable Metal-Organic Frameworks: Porous Crystals and Thin Film Devices

Total Cost €

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EC-Contrib. €

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Partnership

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 chem-fs-MOF project word cloud

Explore the words cloud of the chem-fs-MOF project. It provides you a very rough idea of what is the project "chem-fs-MOF" about.

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Project "chem-fs-MOF" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAT DE VALENCIA 

Organization address
address: AVENIDA BLASCO IBANEZ 13
city: VALENCIA
postcode: 46010
website: www.uv.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 1˙527˙351 €
 EC max contribution 1˙527˙351 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2016-STG
 Funding Scheme ERC-STG
 Starting year 2017
 Duration (year-month-day) from 2017-01-01   to  2021-12-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE VALENCIA ES (VALENCIA) coordinator 1˙527˙351.00

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 Project objective

Metal-Organic-Frameworks (MOFs) offer appealing advantages over classical solids from combination of high surface areas with the crystallinity of inorganic materials and the synthetic versatility (unlimited combination of metals and linkers for fine tuning of properties) and processability of organic materials. Provided chemical stability, I expect combination of porosity with manipulable electrical and optical properties to open a new world of possibilities, with MOFs playing an emerging role in fields of key environmental value like photovoltaics, photocatalysis or electrocatalysis. The conventional insulating character of MOFs and their poor chemical stability (only a minimum fraction are hydrolytically stable) are arguably the two key limitations hindering further development in this context. With chem-fs-MOF I expect to deliver: 1. New synthetic routes specifically designed for producing new, hydrolytically stable Fe(III) and Ti(IV)-MOFs (new synthetic platforms for new materials). 2. More advanced crystalline materials to feature tunable function by chemical manipulation of MOF’s optical/electrical properties and pore activity (function-led chemical engineering). 3. High-quality ultrathin films, reliant on the transfer of single-layers, alongside establishing the techniques required for evaluating their electric properties (key to device integration). Recent works on graphene and layered dichalcogenides anticipate the benefits of nanostructuration for more efficient optoelectronic devices. Notwithstanding great potential, this possibility remains still unexplored for MOFs. Overall, I seek to exploit MOFs’ unparalleled chemical/structural flexibility to produce advanced crystalline materials that combine hydrolytical stability and tunable performance to be used in environmentally relevant applications like visible light photocatalysis. This is an emerging research front that holds great potential for influencing future R&D in Chemistry and Materials Science.

 Publications

year authors and title journal last update
List of publications.
2019 Alejandro Nuñez-Lopez, Marta Galbiati, Natalia M. Padial, Carolina R. Ganivet, Sergio Tatay, Emilio Pardo, Donatella Armentano, Carlos Martí-Gastaldo
Direct Visualization of Pyrrole Reactivity upon Confinement within a Cyclodextrin Metal-Organic Framework
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201904890
Angewandte Chemie International Edition 2019-09-04
2019 Víctor Rubio-Giménez, Carlos Bartual-Murgui, Marta Galbiati, Alejandro Núñez-López, Javier Castells-Gil, Benoit Quinard, Pierre Seneor, Edwige Otero, Philippe Ohresser, Andrés Cantarero, Eugenio Coronado, José Antonio Real, Richard Mattana, Sergio Tatay, Carlos Martí-Gastaldo
Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films
published pages: 4038-4047, ISSN: 2041-6520, DOI: 10.1039/c8sc04935a
Chemical Science 10/14 2019-09-04
2018 Javier Castells-Gil, Natalia M. Padial, Carlos Martí-Gastaldo
Structural reorganization in a hydrogen-bonded organic framework
published pages: 16138-16143, ISSN: 1144-0546, DOI: 10.1039/c8nj02738b
New Journal of Chemistry 42/19 2019-09-04
2018 Javier Castells-Gil, José J. Baldoví, Carlos Martí-Gastaldo, Guillermo Mínguez Espallargas
Implementation of slow magnetic relaxation in a SIM-MOF through a structural rearrangement
published pages: 14734-14740, ISSN: 1477-9226, DOI: 10.1039/c8dt03421d
Dalton Transactions 47/41 2019-09-04
2018 Javier Castells-Gil, Fernando Novio, Natalia M. Padial, Sergio Tatay, Daniel Ruíz-Molina, Carlos Martí-Gastaldo
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
published pages: e58052, ISSN: 1940-087X, DOI: 10.3791/58052
Journal of Visualized Experiments 139 2019-09-04
2019 Craig T. Stoppiello, Helena Isla, Marta Martínez-Abadía, Michael W. Fay, Christopher D. J. Parmenter, Martin J. Roe, Belén Lerma-Berlanga, Carlos Martí-Gastaldo, Aurelio Mateo-Alonso, Andrei N. Khlobystov
Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer
published pages: 2848-2854, ISSN: 2040-3364, DOI: 10.1039/c8nr10086a
Nanoscale 11/6 2019-09-04
2018 José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo
Peptide metal–organic frameworks under pressure: flexible linkers for cooperative compression
published pages: 10654-10659, ISSN: 1477-9226, DOI: 10.1039/c8dt01765d
Dalton Transactions 47/31 2019-09-04
2019 Jose Navarro, Neyvis Almora Barrios, Belén Lerma Berlanga, J. Javier Ruiz-Pernía, Victor Armando Lorenz Fonfria, Iñaki Tuñón, Carlos Martí-Gastaldo
Translocation of Enzymes into a Mesoporous MOF for Enhanced Catalytic Activity Under Extreme Conditions
published pages: , ISSN: 2041-6520, DOI: 10.1039/c9sc00082h
Chemical Science 2019-09-04
2019 Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Ivan da Silva, Diego Mateo, Josep Albero, Hermenegildo García, Carlos Martí-Gastaldo
De novo synthesis of mesoporous photoactive titanium( iv )–organic frameworks with MIL-100 topology
published pages: 4313-4321, ISSN: 2041-6520, DOI: 10.1039/c8sc05218b
Chemical Science 10/15 2019-09-04
2018 José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo
Peptide metal–organic frameworks under pressure: flexible linkers for cooperative compression
published pages: , ISSN: 1477-9226, DOI: 10.1039/C8DT01765D
Dalton Transactions 2019-06-13
2017 Javier Castells-Gil, Fernando Novio, Natalia M. Padial, Sergio Tatay, Daniel Ruíz-Molina, Carlos Martí-Gastaldo
Surface Functionalization of Metal–Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance
published pages: 44641-44648, ISSN: 1944-8244, DOI: 10.1021/acsami.7b15564
ACS Applied Materials & Interfaces 9/51 2019-06-13
2017 José Navarro-Sánchez, Ana I. Argente-García, Yolanda Moliner-Martínez, Daniel Roca-Sanjuán, Dmytro Antypov, Pilar Campíns-Falcó, Matthew J. Rosseinsky, Carlos Martí-Gastaldo
Peptide Metal–Organic Frameworks for Enantioselective Separation of Chiral Drugs
published pages: 4294-4297, ISSN: 0002-7863, DOI: 10.1021/jacs.7b00280
Journal of the American Chemical Society 139/12 2019-06-13
2017 Víctor Rubio-Giménez, Joao C. Waerenborgh, Juan M. Clemente-Juan, Carlos Martí-Gastaldo
Spontaneous Magnetization in Heterometallic NiFe-MOF-74 Microporous Magnets by Controlled Iron Doping
published pages: 6181-6185, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.7b01601
Chemistry of Materials 29/15 2019-06-13
2018 Marc Morant-Giner, Roger Sanchis-Gual, Jorge Romero, Antonio Alberola, Leticia García-Cruz, Said Agouram, Marta Galbiati, Natalia M. Padial, João C. Waerenborgh, Carlos Martí-Gastaldo, Sergio Tatay, Alicia Forment-Aliaga, Eugenio Coronado
Prussian Blue@MoS 2 Layer Composites as Highly Efficient Cathodes for Sodium- and Potassium-Ion Batteries
published pages: 1706125, ISSN: 1616-301X, DOI: 10.1002/adfm.201706125
Advanced Functional Materials 28/27 2019-06-13
2018 Víctor Rubio-Giménez, Marta Galbiati, Javier Castells-Gil, Neyvis Almora-Barrios, José Navarro-Sánchez, Garin Escorcia-Ariza, Michele Mattera, Thomas Arnold, Jonathan Rawle, Sergio Tatay, Eugenio Coronado, Carlos Martí-Gastaldo
Bottom-Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films
published pages: 1704291, ISSN: 0935-9648, DOI: 10.1002/adma.201704291
Advanced Materials 30/10 2019-06-13
2018 Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Josep Albero, A. Rabdel Ruiz-Salvador, Javier González-Platas, Hermenegildo García, Carlos Martí-Gastaldo
Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
published pages: 8453-8457, ISSN: 1433-7851, DOI: 10.1002/anie.201802089
Angewandte Chemie International Edition 57/28 2019-06-13

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