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Multifunctional Spin Crossover Materials

Total Cost €


EC-Contrib. €






Project "SPINSWITCH" data sheet

The following table provides information about the project.


Organization address
postcode: 720229

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Romania [RO]
 Project website
 Total cost 954˙000 €
 EC max contribution 954˙000 € (100%)
 Programme 1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge)
 Code Call H2020-MSCA-RISE-2016
 Funding Scheme MSCA-RISE
 Starting year 2017
 Duration (year-month-day) from 2017-01-01   to  2020-12-31


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
2    UKRORGSYNTEZ UA (KYIV) participant 360˙000.00
3    SRL POLIVALENT-95 MD (CHISINAU) participant 126˙000.00
6    UNIVERSITAT DE VALENCIA ES (VALENCIA) participant 94˙500.00


 Project objective

This project deals with an exchange programme of seven research teams with the aim to establish and consolidate a network for the design of innovative multifunctional materials based upon iron(II) spin crossover complexes: their synthesis, magnetic and spectroscopic studies, investigations on their crystalline, liquid crystalline and morphological structures, pressure effects on spin crossover properties and, particularly, their implementation into pressure sensors. The synthetic part of this project aims to access novel types of crystalline and liquid crystalline spin crossover complexes, hybrid luminescent materials, photo-switchable liquid crystalline compounds, composites and nano-objects of original morphologies and transition characteristics. These switchable materials will become a matter of different experiments under pressure: magnetic and Mӧssbauer measurements under hydrostatic pressure and optical experiments in a gas pressure cell. This will allow to reach an important impact on the synthesis of new bistable materials, on their behaviour under pressure, and to make them an active part of different pressure sensors. The academic participants involved in this work have collaborated on joint projects and have co-authored several scientific papers. The two industrial institutions have a recognized expertise in organic and material synthesis, commercialization, as well possessing experience on elaboration of spin transition materials. The establishment of this joint exchange programme will promote and strengthen the complementarity of the participants and will stimulate cross-fertilization, thus forming an excellent centre of synergy in research, innovation and technology in the area of functional materials. This network offers a complete training in the synthesis and characterization of new spin crossover materials for various applications.


List of deliverables.
Progress Report 1 Documents, reports 2019-05-31 10:32:53
Two scientific papers on the topic of WP1 Websites, patent fillings, videos etc. 2019-05-31 10:32:51
Internet website Websites, patent fillings, videos etc. 2019-05-31 10:45:20

Take a look to the deliverables list in detail:  detailed list of SPINSWITCH deliverables.


year authors and title journal last update
List of publications.
2019 Olesia I. Kucheriv, Diana D. Barakhtii, Sergey O. Malinkin, Sergiu Shova, Il\'ya A. Gural\'skiy
Crystal structure of catena -poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]
published pages: 1149-1152, ISSN: 2056-9890, DOI: 10.1107/s2056989019009678
Acta Crystallographica Section E Crystallographic Communications 75/8 2020-01-28
2019 Maksym Seredyuk, Kateryna Znovjyak, Igor O. Fritsky, Tatiana Y. Sliva, Mykola S. Slobodyanik
Crystal structure and magnetic properties of bis[butyltris(1 H -pyrazol-1-yl)borato]iron(II)
published pages: 1327-1330, ISSN: 2056-9890, DOI: 10.1107/s2056989019011137
Acta Crystallographica Section E Crystallographic Communications 75/9 2020-01-29
2019 Il\'ya A. Gural\'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel
Pyridazine-Supported Polymeric Cyanometallates with Spin Transitions
published pages: 4532-4537, ISSN: 1434-1948, DOI: 10.1002/ejic.201900782
European Journal of Inorganic Chemistry 2019/42 2020-01-28
2019 Alin-Ciprian Bas, Xavier Thompson, Lionel Salmon, Christophe Thibault, Gábor Molnár, Oleg Palamarciuc, Lucie Routaboul, Azzedine Bousseksou
Bilayer Thin Films That Combine Luminescent and Spin Crossover Properties for an Efficient and Reversible Fluorescence Switching
published pages: 28, ISSN: 2312-7481, DOI: 10.3390/magnetochemistry5020028
Magnetochemistry 5/2 2019-12-16
2019 Alin-Ciprian Bas, Victoria Shalabaeva, Xavier Thompson, Laure Vendier, Lionel Salmon, Christophe Thibault, Gábor Molnár, Lucie Routaboul, Azzedine Bousseksou
Effects of solvent vapor annealing on the crystallinity and spin crossover properties of thin films of [Fe(HB(tz)3)2]
published pages: 525-533, ISSN: 1631-0748, DOI: 10.1016/j.crci.2019.03.002
Comptes Rendus Chimie 22/6-7 2019-12-16
2018 Ana B. Gaspar, Gábor Molnár, Aurelian Rotaru, Helena J. Shepherd
Pressure effect investigations on spin-crossover coordination compounds
published pages: 1095-1120, ISSN: 1631-0748, DOI: 10.1016/j.crci.2018.07.010
Comptes Rendus Chimie 21/12 2019-10-08
2019 Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio A Real Cabezos
Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material
published pages: 3807–3816, ISSN: 2041-6520, DOI: 10.1039/c8sc05256e
Chemical Science 10 2019-10-08
2018 Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard
Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material
published pages: 12870-12876, ISSN: 0002-7863, DOI: 10.1021/jacs.8b06042
Journal of the American Chemical Society 140/40 2019-10-08
2019 Kateryna Znovjyak, Igor O. Fritsky, Iryna A. Golenya, Tatiana Y. Sliva, Matti Haukka
Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)
published pages: 358-361, ISSN: 2056-9890, DOI: 10.1107/s2056989019001531
Acta Crystallographica Section E Crystallographic Communications 75/3 2019-05-14
2019 Volodymyr M. Hiiuk, Sergiu Sova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il\'ya A. Gural\'skiy
Room Temperature Hysteretic Spin Crossover in a New Cyanoheterometallic Framework
published pages: , ISSN: 1359-7345, DOI: 10.1039/c8cc10260k
Chemical Communications 2019-05-14
2017 Andrei Diaconu, Simona-Lacramioara Lupu, Ionela Rusu, Ioan-Marian Risca, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou, Philippe Demont, Aurelian Rotaru
Piezoresistive Effect in the [Fe(Htrz) 2 (trz)](BF 4 ) Spin Crossover Complex
published pages: 3147-3151, ISSN: 1948-7185, DOI: 10.1021/acs.jpclett.7b01111
The Journal of Physical Chemistry Letters 8/13 2019-06-11
2017 Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real
Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds
published pages: 13535-13546, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.7b02272
Inorganic Chemistry 56/21 2019-06-11
2018 Victoria Shalabaeva, Karl Ridier, Sylvain Rat, Maria D. Manrique-Juarez, Lionel Salmon, Isabelle Séguy, Aurelian Rotaru, Gábor Molnár, Azzedine Bousseksou
Room temperature current modulation in large area electronic junctions of spin crossover thin films
published pages: 13301, ISSN: 0003-6951, DOI: 10.1063/1.5017458
Applied Physics Letters 112/1 2019-06-11
2017 Volodymyr M. Hiiuk, Diana D. Barakhty, Sergiu Shova, Ruslan A. Polunin, Il\'ya A. Gural\'skiy
Crystal structure of catena -poly[[[tetraaquairon(II)]- trans -μ-1,2-bis(pyridin-4-yl)ethene-κ 2 N : N ′] bis( p -toluenesulfonate) methanol disolvate]
published pages: 1977-1980, ISSN: 2056-9890, DOI: 10.1107/s2056989017017054
Acta Crystallographica Section E Crystallographic Communications 73/12 2019-06-11

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