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Managing trIplets for fLuorescence in ORganics: Towards a predictive moDel (MILORD)

Total Cost €


EC-Contrib. €






 MILORD project word cloud

Explore the words cloud of the MILORD project. It provides you a very rough idea of what is the project "MILORD" about.

mostly    kinetics    crossing    alternative    activated    fundamental    device    collaborative    excited    guide    oleds    molecular    thermally    mechanistic    property    reverse    diffusion    metal    host    picture    light    statistical    electrically    discovery    hope    25    diodes    trial    theoretical    fellow    error    relying    generation    platinum    explore    utilize    efforts    featuring    contain    insights    singlet    competing    materials    absence    fluorescence    ultimately    medium    emitters    reported    bottleneck    synthetic    tadf    triplet    rare    energetics    metals    architectures    model    intersystem    electroluminescence    efficient    strategies    decades    efficiencies    spin    multiscale    risc    original    singlets    solid    minimize    nature    describe    structure    oled    interactions    nowadays    network    organic    underlying    display    excitons    delayed    strategy    last    mechanism    milord    relationships    expensive    iridium    emitting    integrating    triplets    few    losses    demonstrated    realistic    commercial   

Project "MILORD" data sheet

The following table provides information about the project.


Organization address
address: PLACE DU PARC 20
city: MONS
postcode: 7000

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Belgium [BE]
 Total cost 172˙800 €
 EC max contribution 172˙800 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-11-01   to  2019-11-30


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITE DE MONS BE (MONS) coordinator 172˙800.00


 Project objective

The research in the field of organic light-emitting diodes (OLEDs) has greatly advanced over the last decades, driven by the potential of OLED technology for various display applications. Yet, today, most of the commercial OLED devices contain expensive rare metals like Iridium and Platinum. An alternative promising strategy is based on the use of all-organic emitters, featuring the recently reported thermally activated delayed fluorescence (TADF) mechanism. Relying on a reverse intersystem crossing (RISC) process, TADF-based OLEDs may utilize all electrically generated singlet and triplet excitons, going well beyond the 25% spin statistical bottleneck of organic electroluminescence. Nowadays, however, only a few TADF-based OLEDs have demonstrated efficiencies comparable to the best metal-organic materials. Research efforts so far have been mostly based on a trial-and-error approach in absence of a solid fundamental understanding of the underlying processes. The project MILORD aims at providing a comprehensive picture of the TADF mechanism through the use of an original multiscale modelling approach, going all the way from the molecular to the device scale. We will explore the energetics and nature of the involved excited states, describe the kinetics of competing processes, and model the diffusion and interactions of singlets and triplets in a realistic medium. The results of MILORD will provide detailed mechanistic insights into the TADF process, which will ultimately allow us to identify structure-property relationships and propose new strategies to minimize losses. By integrating the research into a large collaborative network around the Host and the Fellow, we hope that our theoretical work will guide synthetic efforts towards the discovery of a new generation of more efficient materials and device architectures.


year authors and title journal last update
List of publications.
2019 Julius A. Knöller, Guoyun Meng, Xiang Wang, David Hall, Anton Pershin, David Beljonne, Yoann Olivier, Sabine Laschat, Eli Zysman-Colman, Suning Wang
Intramolecular Borylation via Sequential B−Mes Bond Cleavage for the Divergent Synthesis of B,N,B-Doped Benzo[4]helicenes
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201912340
Angewandte Chemie International Edition 2020-02-06
2019 David Hall, Subeesh Madayanad Suresh, Paloma L. dos Santos, Eimantas Duda, Sergey Bagnich, Anton Pershin, Pachaiyappan Rajamalli, David B. Cordes, Alexandra M. Z. Slawin, David Beljonne, Anna Köhler, Ifor D. W. Samuel, Yoann Olivier, Eli Zysman‐Colman
Improving Processability and Efficiency of Resonant TADF Emitters: A Design Strategy
published pages: 1901627, ISSN: 2195-1071, DOI: 10.1002/adom.201901627
Advanced Optical Materials 8/2 2020-02-06
2019 Anton Pershin, David Hall, Vincent Lemaur, Juan-Carlos Sancho-Garcia, Luca Muccioli, Eli Zysman-Colman, David Beljonne, Yoann Olivier
Highly emissive excitons with reduced exchange energy in thermally activated delayed fluorescent molecules
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-08495-5
Nature Communications 10/1 2020-02-06
2019 Naoyuki Nishimura, Victor Gray, Jesse R. Allardice, Zhilong Zhang, Anton Pershin, David Beljonne, Akshay Rao
Photon Upconversion from Near-Infrared to Blue Light with TIPS-Anthracene as an Efficient Triplet–Triplet Annihilator
published pages: 660-664, ISSN: 2639-4979, DOI: 10.1021/acsmaterialslett.9b00287
ACS Materials Letters 1/6 2020-02-06
2019 Claire Tonnelé, Anton Pershin, Sai Manoj Gali, Aurélien Lherbier, Jean-Christophe Charlier, Frédéric Castet, Luca Muccioli, David Beljonne
Atomistic simulations of charge transport in photoswitchable organic-graphene hybrids
published pages: 35001, ISSN: 2515-7639, DOI: 10.1088/2515-7639/ab1314
Journal of Physics: Materials 2/3 2020-02-06

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