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ET-PHOTOX TERMINATED

Functionalization of ethereal C-O Bonds Enabled by Metallaphotoredox Catalysis

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 ET-PHOTOX project word cloud

Explore the words cloud of the ET-PHOTOX project. It provides you a very rough idea of what is the project "ET-PHOTOX" about.

position    conceptuality    aside    skills    promise    harsh    scientific    30    prompted    instances    applicable    direct    dioxide    catalysis    reagents    functionalization    arena    organometallic    bond    earth    funcionalization    native    start    infancy    stoichiometric    innovative    competences    groups    organic    acceptor    chemists    natural    bonds    area    photoredox    extended    coupling    technologies    ethers    events    training    quality    nickel    carbon    received    abundance    synthesis    catalytic    mild    academic    cleavage    nucleophiles    challenged    prefunctionalized    donor    activation    opportunity    tactics    revolutionize    abundant    complexation    activated    career    realized    devise    practicality    holds    transferable    fossil    inert    lignin    scenarios    et    synergistic    functionalizing    metal    functional    considerable    candidate    independent    prospective    ethereal    electron    unlock    ubiquitous    confined    aryl    unconceivable    biopolymer    photox   

Project "ET-PHOTOX" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 158˙121 €
 EC max contribution 158˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 158˙121.00

Map

 Project objective

The direct utilization of native functional groups without the need for prefunctionalized holds considerable promise to revolutionize organic synthesis. While significant advances have been realized within the area of C-H activation, the functionalization of inert C-O bonds in aryl ethers is still at its infancy. Prompted by the natural abundance of aryl ethers in Lignin, the second most abundant biopolymer (30% of non-fossil organic carbon on earth), chemists have been challenged to devise, conceptuality and practicality aside, mild, general and widely applicable catalytic technologies for ethereal C-O funcionalization. At present, however, these technologies remain confined to the use of rather activated extended p-systems, stoichiometric metal reagents and, in many instances, harsh conditions. ET-PHOTOX will offer an innovative and challenging approach for functionalizing aryl C-O bonds by merging nickel catalysis and photoredox catalysis via electron donor-acceptor complexation events. Such synergistic catalysis will unlock unconceivable scenarios within the C-O bond-cleavage arena, including the use of non-extended p-systems, non-organometallic based nucleophiles or even carbon dioxide as coupling partner. Therefore, this project holds potential to change concepts in catalysis, allowing new tactics to be implemented in organic synthesis from ubiquitous C-O bonds, thus enhancing the ever-growing quality of the European research. The prospective impact of ET-PHOTOX, together with the new scientific, technical training, competences and transferable skills received will position the candidate with a unique opportunity to start an independent career at a European academic institution after the execution of the project.

 Publications

year authors and title journal last update
List of publications.
2019 Basudev Sahoo, Peter Bellotti, Francisco Juliá‐Hernández, Qing‐Yuan Meng, Stefano Crespi, Burkhard König, Ruben Martin
Site‐Selective, Remote sp 3 C−H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis
published pages: 9001-9005, ISSN: 0947-6539, DOI: 10.1002/chem.201902095
Chemistry – A European Journal 25/38 2020-03-06

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