Opendata, web and dolomites

ET-PHOTOX TERMINATED

Functionalization of ethereal C-O Bonds Enabled by Metallaphotoredox Catalysis

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

0

 ET-PHOTOX project word cloud

Explore the words cloud of the ET-PHOTOX project. It provides you a very rough idea of what is the project "ET-PHOTOX" about.

prospective    ethers    cleavage    start    lignin    stoichiometric    mild    instances    scenarios    abundance    ethereal    considerable    abundant    photoredox    career    extended    unconceivable    coupling    functionalization    catalytic    scientific    biopolymer    et    independent    quality    metal    functionalizing    infancy    aryl    devise    revolutionize    prefunctionalized    opportunity    position    transferable    harsh    conceptuality    skills    catalysis    area    donor    confined    complexation    arena    reagents    academic    natural    dioxide    organic    received    promise    bond    applicable    funcionalization    candidate    competences    training    direct    30    prompted    tactics    activation    ubiquitous    bonds    unlock    photox    chemists    challenged    holds    functional    practicality    activated    synthesis    aside    electron    inert    acceptor    nickel    nucleophiles    fossil    groups    events    earth    synergistic    native    carbon    technologies    innovative    realized    organometallic   

Project "ET-PHOTOX" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 158˙121 €
 EC max contribution 158˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 158˙121.00

Map

 Project objective

The direct utilization of native functional groups without the need for prefunctionalized holds considerable promise to revolutionize organic synthesis. While significant advances have been realized within the area of C-H activation, the functionalization of inert C-O bonds in aryl ethers is still at its infancy. Prompted by the natural abundance of aryl ethers in Lignin, the second most abundant biopolymer (30% of non-fossil organic carbon on earth), chemists have been challenged to devise, conceptuality and practicality aside, mild, general and widely applicable catalytic technologies for ethereal C-O funcionalization. At present, however, these technologies remain confined to the use of rather activated extended p-systems, stoichiometric metal reagents and, in many instances, harsh conditions. ET-PHOTOX will offer an innovative and challenging approach for functionalizing aryl C-O bonds by merging nickel catalysis and photoredox catalysis via electron donor-acceptor complexation events. Such synergistic catalysis will unlock unconceivable scenarios within the C-O bond-cleavage arena, including the use of non-extended p-systems, non-organometallic based nucleophiles or even carbon dioxide as coupling partner. Therefore, this project holds potential to change concepts in catalysis, allowing new tactics to be implemented in organic synthesis from ubiquitous C-O bonds, thus enhancing the ever-growing quality of the European research. The prospective impact of ET-PHOTOX, together with the new scientific, technical training, competences and transferable skills received will position the candidate with a unique opportunity to start an independent career at a European academic institution after the execution of the project.

 Publications

year authors and title journal last update
List of publications.
2019 Basudev Sahoo, Peter Bellotti, Francisco Juliá‐Hernández, Qing‐Yuan Meng, Stefano Crespi, Burkhard König, Ruben Martin
Site‐Selective, Remote sp 3 C−H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis
published pages: 9001-9005, ISSN: 0947-6539, DOI: 10.1002/chem.201902095
Chemistry – A European Journal 25/38 2020-03-06

Are you the coordinator (or a participant) of this project? Plaese send me more information about the "ET-PHOTOX" project.

For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.

Send me an  email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.

Thanks. And then put a link of this page into your project's website.

The information about "ET-PHOTOX" are provided by the European Opendata Portal: CORDIS opendata.

More projects from the same programme (H2020-EU.1.3.2.)

DiMaS (2019)

Retrospective genomic analyses of shortfin Mako shark (Isurus oxyrinchus) using DNA from archived jaws

Read More  

EPIC (2019)

Evolution of Planktonic Gastropod Calcification

Read More  

MathematicsAnalogies (2019)

Mathematics Analogies

Read More