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ET-PHOTOX SIGNED

Functionalization of ethereal C-O Bonds Enabled by Metallaphotoredox Catalysis

Total Cost €

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EC-Contrib. €

0

Partnership

0

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 ET-PHOTOX project word cloud

Explore the words cloud of the ET-PHOTOX project. It provides you a very rough idea of what is the project "ET-PHOTOX" about.

ethers    photox    technologies    synthesis    carbon    bonds    extended    catalysis    organic    aryl    holds    et   

Project "ET-PHOTOX" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 158˙121 €
 EC max contribution 158˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme /MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-05-01   to  2020-04-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 158˙121.00

Mappa

 Project objective

The direct utilization of native functional groups without the need for prefunctionalized holds considerable promise to revolutionize organic synthesis. While significant advances have been realized within the area of C-H activation, the functionalization of inert C-O bonds in aryl ethers is still at its infancy. Prompted by the natural abundance of aryl ethers in Lignin, the second most abundant biopolymer (30% of non-fossil organic carbon on earth), chemists have been challenged to devise, conceptuality and practicality aside, mild, general and widely applicable catalytic technologies for ethereal C-O funcionalization. At present, however, these technologies remain confined to the use of rather activated extended p-systems, stoichiometric metal reagents and, in many instances, harsh conditions. ET-PHOTOX will offer an innovative and challenging approach for functionalizing aryl C-O bonds by merging nickel catalysis and photoredox catalysis via electron donor-acceptor complexation events. Such synergistic catalysis will unlock unconceivable scenarios within the C-O bond-cleavage arena, including the use of non-extended p-systems, non-organometallic based nucleophiles or even carbon dioxide as coupling partner. Therefore, this project holds potential to change concepts in catalysis, allowing new tactics to be implemented in organic synthesis from ubiquitous C-O bonds, thus enhancing the ever-growing quality of the European research. The prospective impact of ET-PHOTOX, together with the new scientific, technical training, competences and transferable skills received will position the candidate with a unique opportunity to start an independent career at a European academic institution after the execution of the project.

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The information about "ET-PHOTOX" are provided by the European Opendata Portal: CORDIS opendata.

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