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FC2DMOF SIGNED

Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks

Total Cost €

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EC-Contrib. €

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Partnership

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 FC2DMOF project word cloud

Explore the words cloud of the FC2DMOF project. It provides you a very rough idea of what is the project "FC2DMOF" about.

led    catalysis    intrinsic    employing    vapor    magnetic    1e    conjugated    inorganic    exfoliation    quality    air    liquid    superior    frameworks    samples    3d    clean    synthesize    nanosheets    c2dmof    structures    device    vdwhs    interaction    versatile    solvothermal    spin    immature    area    charge    cvd    single    separation    metal    electronic    integration    chemical    delineation    der    monomers    synthesis    bulk    relationships    plane    temperature    weak    ground    band    designs    mofs    elusive    lack    breaking    types    interfacial    crystalline    spintronics    deposition    structural    disclose    highlighted    explore    layer    gaps    magnetism    electronics    storage    crystals    conductive    structure    few    sizes    film    mechanism    engineering    semi    strategies    films    realize    geometries    unprecedented    tune    1000    stacked    lt    cm    organic    transport    electrochemical    conductivity    depended    difficult    van    2d    functions    heterostructures    pore    performance    c2dmofs    route    gas    subsequent    achievements    limited    waals   

Project "FC2DMOF" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙500˙000 €
 EC max contribution 1˙500˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-STG
 Funding Scheme ERC-STG
 Starting year 2020
 Duration (year-month-day) from 2020-02-01   to  2025-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 1˙500˙000.00

Map

 Project objective

Metal-organic frameworks (MOFs) have been highlighted for catalysis, gas storage and separation. However, due to low conductivity (<1E-8 S/cm), weak magnetic interaction as well as difficult device integration, the application of bulk 3D MOFs in (spin-)electronics is challenging. Recent advances disclose that the designs of conjugated 2D MOFs (C2DMOFs) have led to improved intrinsic conductivity (up to 1000 S/cm). However, the related research remains immature due to lack of high-quality film samples, very limited structural types and elusive transport mechanism. In this project, we will develop unprecedented magnetic (semi-)conductive C2DMOFs and accomplish electronic/magnetic structure engineering for functions in electronics and spintronics. Here, we will synthesize novel conjugated monomers to tune geometries and pore sizes of C2DMOFs, thus achieving in-plane engineering on charge and spin distribution. We will develop versatile synthesis strategies towards highly crystalline C2DMOF films/nanosheets: (1) develop solvothermal synthesis and subsequent electrochemical exfoliation of layer-stacked bulk samples into 2D nanosheets; (2) develop air/liquid and liquid/liquid interfacial synthesis of large-area single-/few-layer films; (3) particularly establish a ground-breaking chemical vapor deposition (CVD) synthesis route for “clean” single-crystalline films. We will further establish unprecedented C2DMOF-based 2D-2D van der Waals heterostructures (vdWHs) with other inorganic 2D crystals to realize out-of-plane engineering on band gaps and unique interfacial transport characteristics. By employing the developed C2DMOFs and vdWHs, we will explore magnetism and temperature-/magnetic field-depended charge transport properties. As the key achievements, we expect to establish novel electronic/magnetic structures and general synthesis strategies, delineation of reliable structure-transport relationships and superior device performance of C2DMOFs.

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