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FC2DMOF SIGNED

Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks

Total Cost €

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EC-Contrib. €

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Partnership

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 FC2DMOF project word cloud

Explore the words cloud of the FC2DMOF project. It provides you a very rough idea of what is the project "FC2DMOF" about.

delineation    gaps    organic    difficult    vdwhs    interfacial    van    spintronics    types    semi    air    quality    relationships    films    der    structures    solvothermal    1e    depended    chemical    charge    electrochemical    magnetism    exfoliation    separation    mofs    pore    intrinsic    conductive    crystalline    layer    route    nanosheets    c2dmofs    unprecedented    integration    inorganic    cvd    breaking    deposition    geometries    band    superior    heterostructures    c2dmof    versatile    clean    sizes    lt    spin    highlighted    film    achievements    limited    strategies    conductivity    subsequent    employing    structural    3d    metal    interaction    monomers    1000    stacked    explore    ground    device    elusive    mechanism    samples    performance    weak    vapor    plane    cm    immature    waals    led    electronic    crystals    liquid    storage    bulk    functions    designs    engineering    2d    single    frameworks    magnetic    transport    realize    conjugated    synthesis    electronics    disclose    synthesize    structure    gas    few    lack    temperature    area    tune    catalysis   

Project "FC2DMOF" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙500˙000 €
 EC max contribution 1˙500˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-STG
 Funding Scheme ERC-STG
 Starting year 2020
 Duration (year-month-day) from 2020-02-01   to  2025-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 1˙500˙000.00

Map

 Project objective

Metal-organic frameworks (MOFs) have been highlighted for catalysis, gas storage and separation. However, due to low conductivity (<1E-8 S/cm), weak magnetic interaction as well as difficult device integration, the application of bulk 3D MOFs in (spin-)electronics is challenging. Recent advances disclose that the designs of conjugated 2D MOFs (C2DMOFs) have led to improved intrinsic conductivity (up to 1000 S/cm). However, the related research remains immature due to lack of high-quality film samples, very limited structural types and elusive transport mechanism. In this project, we will develop unprecedented magnetic (semi-)conductive C2DMOFs and accomplish electronic/magnetic structure engineering for functions in electronics and spintronics. Here, we will synthesize novel conjugated monomers to tune geometries and pore sizes of C2DMOFs, thus achieving in-plane engineering on charge and spin distribution. We will develop versatile synthesis strategies towards highly crystalline C2DMOF films/nanosheets: (1) develop solvothermal synthesis and subsequent electrochemical exfoliation of layer-stacked bulk samples into 2D nanosheets; (2) develop air/liquid and liquid/liquid interfacial synthesis of large-area single-/few-layer films; (3) particularly establish a ground-breaking chemical vapor deposition (CVD) synthesis route for “clean” single-crystalline films. We will further establish unprecedented C2DMOF-based 2D-2D van der Waals heterostructures (vdWHs) with other inorganic 2D crystals to realize out-of-plane engineering on band gaps and unique interfacial transport characteristics. By employing the developed C2DMOFs and vdWHs, we will explore magnetism and temperature-/magnetic field-depended charge transport properties. As the key achievements, we expect to establish novel electronic/magnetic structures and general synthesis strategies, delineation of reliable structure-transport relationships and superior device performance of C2DMOFs.

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