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FC2DMOF SIGNED

Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks

Total Cost €

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EC-Contrib. €

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Partnership

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 FC2DMOF project word cloud

Explore the words cloud of the FC2DMOF project. It provides you a very rough idea of what is the project "FC2DMOF" about.

plane    lt    area    conductivity    breaking    1000    difficult    exfoliation    highlighted    charge    gaps    functions    disclose    structures    types    integration    intrinsic    sizes    electrochemical    organic    quality    bulk    deposition    cm    clean    realize    magnetic    explore    frameworks    air    versatile    mechanism    chemical    films    synthesis    delineation    1e    led    weak    pore    geometries    spintronics    vdwhs    structural    c2dmofs    lack    electronic    few    semi    layer    strategies    achievements    liquid    superior    performance    engineering    band    samples    waals    spin    metal    temperature    gas    route    cvd    depended    nanosheets    magnetism    interfacial    mofs    monomers    c2dmof    relationships    film    catalysis    heterostructures    elusive    conjugated    separation    designs    immature    der    single    2d    structure    crystalline    unprecedented    ground    solvothermal    electronics    stacked    transport    vapor    conductive    van    storage    subsequent    device    inorganic    employing    interaction    crystals    3d    synthesize    tune    limited   

Project "FC2DMOF" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙500˙000 €
 EC max contribution 1˙500˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-STG
 Funding Scheme ERC-STG
 Starting year 2020
 Duration (year-month-day) from 2020-02-01   to  2025-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 1˙500˙000.00

Map

 Project objective

Metal-organic frameworks (MOFs) have been highlighted for catalysis, gas storage and separation. However, due to low conductivity (<1E-8 S/cm), weak magnetic interaction as well as difficult device integration, the application of bulk 3D MOFs in (spin-)electronics is challenging. Recent advances disclose that the designs of conjugated 2D MOFs (C2DMOFs) have led to improved intrinsic conductivity (up to 1000 S/cm). However, the related research remains immature due to lack of high-quality film samples, very limited structural types and elusive transport mechanism. In this project, we will develop unprecedented magnetic (semi-)conductive C2DMOFs and accomplish electronic/magnetic structure engineering for functions in electronics and spintronics. Here, we will synthesize novel conjugated monomers to tune geometries and pore sizes of C2DMOFs, thus achieving in-plane engineering on charge and spin distribution. We will develop versatile synthesis strategies towards highly crystalline C2DMOF films/nanosheets: (1) develop solvothermal synthesis and subsequent electrochemical exfoliation of layer-stacked bulk samples into 2D nanosheets; (2) develop air/liquid and liquid/liquid interfacial synthesis of large-area single-/few-layer films; (3) particularly establish a ground-breaking chemical vapor deposition (CVD) synthesis route for “clean” single-crystalline films. We will further establish unprecedented C2DMOF-based 2D-2D van der Waals heterostructures (vdWHs) with other inorganic 2D crystals to realize out-of-plane engineering on band gaps and unique interfacial transport characteristics. By employing the developed C2DMOFs and vdWHs, we will explore magnetism and temperature-/magnetic field-depended charge transport properties. As the key achievements, we expect to establish novel electronic/magnetic structures and general synthesis strategies, delineation of reliable structure-transport relationships and superior device performance of C2DMOFs.

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