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FC2DMOF SIGNED

Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks

Total Cost €

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EC-Contrib. €

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Partnership

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 FC2DMOF project word cloud

Explore the words cloud of the FC2DMOF project. It provides you a very rough idea of what is the project "FC2DMOF" about.

c2dmofs    quality    versatile    3d    nanosheets    functions    stacked    solvothermal    structures    elusive    gas    bulk    2d    realize    catalysis    exfoliation    c2dmof    breaking    spin    crystals    single    synthesis    band    led    transport    explore    mechanism    air    interaction    der    gaps    delineation    limited    vapor    semi    highlighted    lt    designs    magnetism    employing    intrinsic    crystalline    subsequent    structure    van    conductivity    temperature    area    separation    ground    types    tune    route    frameworks    cvd    metal    conductive    spintronics    vdwhs    synthesize    monomers    strategies    electronics    1e    liquid    films    lack    deposition    weak    waals    storage    superior    relationships    conjugated    samples    unprecedented    mofs    depended    charge    engineering    layer    electrochemical    magnetic    heterostructures    performance    film    chemical    device    sizes    cm    1000    plane    immature    electronic    clean    organic    interfacial    integration    structural    inorganic    disclose    few    geometries    achievements    difficult    pore   

Project "FC2DMOF" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙500˙000 €
 EC max contribution 1˙500˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-STG
 Funding Scheme ERC-STG
 Starting year 2020
 Duration (year-month-day) from 2020-02-01   to  2025-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 1˙500˙000.00

Map

 Project objective

Metal-organic frameworks (MOFs) have been highlighted for catalysis, gas storage and separation. However, due to low conductivity (<1E-8 S/cm), weak magnetic interaction as well as difficult device integration, the application of bulk 3D MOFs in (spin-)electronics is challenging. Recent advances disclose that the designs of conjugated 2D MOFs (C2DMOFs) have led to improved intrinsic conductivity (up to 1000 S/cm). However, the related research remains immature due to lack of high-quality film samples, very limited structural types and elusive transport mechanism. In this project, we will develop unprecedented magnetic (semi-)conductive C2DMOFs and accomplish electronic/magnetic structure engineering for functions in electronics and spintronics. Here, we will synthesize novel conjugated monomers to tune geometries and pore sizes of C2DMOFs, thus achieving in-plane engineering on charge and spin distribution. We will develop versatile synthesis strategies towards highly crystalline C2DMOF films/nanosheets: (1) develop solvothermal synthesis and subsequent electrochemical exfoliation of layer-stacked bulk samples into 2D nanosheets; (2) develop air/liquid and liquid/liquid interfacial synthesis of large-area single-/few-layer films; (3) particularly establish a ground-breaking chemical vapor deposition (CVD) synthesis route for “clean” single-crystalline films. We will further establish unprecedented C2DMOF-based 2D-2D van der Waals heterostructures (vdWHs) with other inorganic 2D crystals to realize out-of-plane engineering on band gaps and unique interfacial transport characteristics. By employing the developed C2DMOFs and vdWHs, we will explore magnetism and temperature-/magnetic field-depended charge transport properties. As the key achievements, we expect to establish novel electronic/magnetic structures and general synthesis strategies, delineation of reliable structure-transport relationships and superior device performance of C2DMOFs.

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