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FC2DMOF SIGNED

Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks

Total Cost €

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EC-Contrib. €

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Partnership

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 FC2DMOF project word cloud

Explore the words cloud of the FC2DMOF project. It provides you a very rough idea of what is the project "FC2DMOF" about.

breaking    immature    plane    electrochemical    storage    device    magnetism    2d    depended    pore    unprecedented    explore    synthesis    deposition    mofs    exfoliation    van    c2dmof    realize    superior    employing    chemical    area    semi    led    waals    organic    1000    separation    interfacial    single    1e    interaction    types    functions    temperature    magnetic    structures    route    stacked    inorganic    catalysis    tune    electronics    films    transport    subsequent    gas    monomers    sizes    versatile    weak    disclose    designs    air    3d    electronic    limited    conductivity    solvothermal    highlighted    synthesize    intrinsic    crystals    band    integration    performance    strategies    crystalline    cm    cvd    samples    metal    engineering    lack    clean    bulk    spin    vapor    achievements    charge    layer    liquid    difficult    gaps    ground    relationships    vdwhs    delineation    film    elusive    few    c2dmofs    der    conjugated    spintronics    nanosheets    heterostructures    quality    frameworks    conductive    geometries    mechanism    structural    structure    lt   

Project "FC2DMOF" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙500˙000 €
 EC max contribution 1˙500˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-STG
 Funding Scheme ERC-STG
 Starting year 2020
 Duration (year-month-day) from 2020-02-01   to  2025-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 1˙500˙000.00

Map

 Project objective

Metal-organic frameworks (MOFs) have been highlighted for catalysis, gas storage and separation. However, due to low conductivity (<1E-8 S/cm), weak magnetic interaction as well as difficult device integration, the application of bulk 3D MOFs in (spin-)electronics is challenging. Recent advances disclose that the designs of conjugated 2D MOFs (C2DMOFs) have led to improved intrinsic conductivity (up to 1000 S/cm). However, the related research remains immature due to lack of high-quality film samples, very limited structural types and elusive transport mechanism. In this project, we will develop unprecedented magnetic (semi-)conductive C2DMOFs and accomplish electronic/magnetic structure engineering for functions in electronics and spintronics. Here, we will synthesize novel conjugated monomers to tune geometries and pore sizes of C2DMOFs, thus achieving in-plane engineering on charge and spin distribution. We will develop versatile synthesis strategies towards highly crystalline C2DMOF films/nanosheets: (1) develop solvothermal synthesis and subsequent electrochemical exfoliation of layer-stacked bulk samples into 2D nanosheets; (2) develop air/liquid and liquid/liquid interfacial synthesis of large-area single-/few-layer films; (3) particularly establish a ground-breaking chemical vapor deposition (CVD) synthesis route for “clean” single-crystalline films. We will further establish unprecedented C2DMOF-based 2D-2D van der Waals heterostructures (vdWHs) with other inorganic 2D crystals to realize out-of-plane engineering on band gaps and unique interfacial transport characteristics. By employing the developed C2DMOFs and vdWHs, we will explore magnetism and temperature-/magnetic field-depended charge transport properties. As the key achievements, we expect to establish novel electronic/magnetic structures and general synthesis strategies, delineation of reliable structure-transport relationships and superior device performance of C2DMOFs.

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