FLUOCOORCHEM

Fluorinated Weakly Coordinating Anions for Coordination Chemistry of Unusual Ligands

Coordinatore	INSTITUT JOZEF STEFAN    more  Organization address address: Jamova 39 city: LJUBLJANA postcode: 1000 contact info Titolo: Prof. Nome: Jadran Cognome: Lenar?i? Email: send email Telefono: +386 1 477 3513 Fax: +386 1 477 3906
Nazionalità Coordinatore	Slovenia [SI]
Totale costo	238˙134 €
EC contributo	238˙134 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2013-IOF
Funding Scheme	MC-IOF
Anno di inizio	2014
Periodo (anno-mese-giorno)	2014-07-01   -   2017-06-30

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	INSTITUT JOZEF STEFAN  Organization address address: Jamova 39 city: LJUBLJANA postcode: 1000 contact info Titolo: Prof. Nome: Jadran Cognome: Lenar?i? Email: send email Telefono: +386 1 477 3513 Fax: +386 1 477 3906	SI (LJUBLJANA)	coordinator	238˙134.00

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 Obiettivo del progetto (Objective)

'The aim of the project is to prepare metal-complexes of weakly coordinating anions and unusual ligands (nitrous oxide, dihydrogen trioxide, krypton difluoride, xenon tetrafluoride, xenon difluoride, and hydrogen fluoride) and subject them to single crystal X-ray diffraction in order to obtain a detailed structural information of the ligand (dihydrogen trioxide) or the metal-ligand interaction (nitrous oxide, dihydrogen trioxide, krypton difluoride, xenon tetrafluoride, xenon difluoride, and hydrogen fluoride). The approach of the proposal is based on merging the experimental techniques (low temperature isolation and structural characterisation, especially used and developed in noble gas chemistry) and chemistries (fluorinated super weakly coordinating anions) with the fields (nitrous oxide and dihydrogen trioxide chemistry) where they have not been used before. Fundamental insights on the nature of the interactions between metals and aforementioned ligands (nitrous oxide, dihydrogen trioxide) would have environmental, technological, and implications in biological systems.'