METCOPH
Metallocomplexes of macrocyclic compounds for photonic devices
Total Cost €
0EC-Contrib. €
0Partnership
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Explore the words cloud of the METCOPH project. It provides you a very rough idea of what is the project "METCOPH" about.
Project "METCOPH" data sheet
The following table provides information about the project.
| Coordinator |
INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK
Organization address contact info |
| Coordinator Country | Poland [PL] |
| Project website | http://risemetcoph.eu/ |
| Total cost | 688˙500 € |
| EC max contribution | 688˙500 € (100%) |
| Programme |
1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge) |
| Code Call | H2020-MSCA-RISE-2014 |
| Funding Scheme | MSCA-RISE |
| Starting year | 2015 |
| Duration (year-month-day) | from 2015-01-01 to 2018-12-31 |
Partnership
Take a look of project's partnership.
| # | ||||
|---|---|---|---|---|
| 1 | INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK | PL (WARSZAWA) | coordinator | 360˙000.00 |
| 2 | UNIVERSITAET REGENSBURG | DE (REGENSBURG) | participant | 247˙500.00 |
| 3 | TEL AVIV UNIVERSITY | IL (TEL AVIV) | participant | 81˙000.00 |
| 4 | B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus | BY (Minsk) | partner | 0.00 |
| 5 | V.I.Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine | UA (KYIV) | partner | 0.00 |
Map
Project objective
The key objective of the METCOPH multidisciplinary project is to intensify and consolidate cooperation between several research groups from member states and third countries on topics within the field of fundamental interdisciplinary science. The project combines the basic ideas of organic chemistry, solid state physics, photochemistry and spectroscopy of metallocomplexes of macrocyclic compounds (MMC) for applications in quantum information processing, sensing, switching and amplification. The project aims at focusing mutual efforts of five research groups with extended and complementary competence in their respective research fields and at gathering multidisciplinary and complementary expertise in chemical engineering and investigation of spectroscopy and photochemistry of MMCs for future design of photonic devices (e.g. organic light emitting devices – OLEDs, light emitting electrochemical cells – LECs, sensors, light emitting transistors) based on above mentioned compounds. The physical and chemical mechanisms of manipulation of optical response for these novel compounds will be revealed and analyzed with involving diverse spectroscopic approaches including steady-state and transient absorption, site-selective high-resolution luminescence, Raman scattering, atomic force microscopy and single-objects detection methods at different temperatures ranging from 1.2 K to ambient temperature. The expected results involve fabrication and chemical/photophysical characterisation of MMCs based on various core metals and incorporating various functional organic ligands. One of the key technologies will rely on driving optical transistor with CW and pulsed lasers and will make use of simultaneous excitation of singlet and triplet states of the metallocomplexes of macrocyclic compounds. The new information gained for these newly synthesized MMC systems will have impact on the engineering of novel functional MMCs for application in nanotechnology and photonic devices.
Deliverables
| Progress Report II. | Documents, reports | 2019-09-02 13:50:58 |
| Quantum-chemical calculations of the MMCs | Documents, reports | 2019-09-02 13:50:58 |
| Scaling of properties of the single emitting MMCs | Other | 2019-09-02 13:50:58 |
| Fluorescence and phosphorescence data | Documents, reports | 2019-09-02 13:50:57 |
| Luminescent pincer complexes | Documents, reports | 2019-09-02 13:50:57 |
| Vibrational assignment of investigated compounds | Documents, reports | 2019-09-02 13:50:57 |
| Data of the conformational stability of the MMC | Documents, reports | 2019-09-02 13:50:57 |
| A set of energy level diagrams describing the excitation energy deactivation channels in the case of MMCs | Documents, reports | 2019-09-02 13:50:57 |
| MMCs with out-of-plane ligands | Documents, reports | 2019-09-02 13:50:57 |
| Photostable luminescent MMCs | Documents, reports | 2019-09-02 13:50:57 |
| Free-base organic core and cyclometalating ligands | Documents, reports | 2019-09-02 13:50:57 |
| Progress Report I. | Documents, reports | 2019-09-02 13:50:57 |
Take a look to the deliverables list in detail: detailed list of METCOPH deliverables.
Publications
| year | authors and title | journal | last update |
|---|---|---|---|
| 2018 |
Aleksandr Starukhin, Aleksander Gorski, Michal Kijak Influence of solid matrices on spectral features of metalloporphyrins published pages: 3013, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819003013 |
EPJ Web of Conferences 190 | 2019-09-02 |
| 2018 |
Aleksandr Starukhin, Aleksander Gorski, Tatsiana Pavich, Valerii Kniukshto Spectral features of conjugated bichromophores: porphyrins with curcumin published pages: 4023, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004023 |
EPJ Web of Conferences 190 | 2019-09-02 |
| 2018 |
A. O. Savostianov, I. Yu. Eremchev, A. A. Gorshelev, A. V. Naumov, A. S. Starukhin Wide-Range Spectral Diffusion in Single Mg-Tetraazaporphyrin Molecules in a Polymer Matrix at Cryogenic Temperatures published pages: 406-411, ISSN: 0021-3640, DOI: 10.1134/s002136401807007x |
JETP Letters 107/7 | 2019-09-02 |
| 2018 |
A. S. Starukhin, A. V. Gorski, M. Z. Kijak Spectral Distortions of Metalloporphyrin Forms at Low Temperatures published pages: 1560-1564, ISSN: 1062-8738, DOI: 10.3103/s1062873818120225 |
Bulletin of the Russian Academy of Sciences: Physics 82/12 | 2019-09-02 |
| 2018 |
Aleksandr Savostianov, Ivan Eremchev, Alexei Gorshelev, Sergei Orlov, Oleg Korotayev, Andrei Naumov, Aleksandr Starukhin Structural and time-domain peculiarities of the fluorescence excitation spectra of single Mg-TAP in a polymer at low temperatures published pages: 4019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004019 |
EPJ Web of Conferences 190 | 2019-09-02 |
| 2018 |
Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, Michał Kijak, Jędrzej Solarski, Alexander Semeikin, Tatjana Lyubimova Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002 |
Journal of Photochemistry and Photobiology A: Chemistry 354 | 2019-09-02 |
| 2018 |
Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, Michał Kijak, Jędrzej Solarski, Alexander Semeikin, Tatjana Lyubimova Temperature dependent steric hindrance effects in triplet state relaxation of meso -phenyl-substituted Pd-octaethylporphyrins published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002 |
Journal of Photochemistry and Photobiology A: Chemistry 354 | 2019-09-02 |
| 2017 |
A. Starukhin, V. Knyukshto, A. Gorski, V. Chernii, I. Tretyakova, M. Kijak, P. Kowalska Spectral manifestation of substitution of out-of-plane ligands in metallophtalocyanines published pages: 3044, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713203044 |
EPJ Web of Conferences 132 | 2019-09-02 |
| 2017 |
Marsel Z. Shafikov, Alfiya F. Suleymanova, Rafał Czerwieniec, and Hartmut Yersin Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough published pages: , ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b05175 |
Chemistry of Materials | 2019-09-02 |
| 2017 |
A. Gorski, A. Starukhin, S. Stavrov, S. Gawinkowski, J. Waluk Resonance Raman spectroscopy study of protonated porphyrin published pages: 350-355, ISSN: 1386-1425, DOI: 10.1016/j.saa.2016.09.038 |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 173 | 2019-09-02 |
| 2016 |
Rafał Czerwieniec, Markus J. Leitl, Herbert H.H. Homeier, Hartmut Yersin Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design published pages: 2–28, ISSN: 0010-8545, DOI: 10.1016/j.ccr.2016.06.016 |
Coordination Chemistry Reviews | 2019-09-02 |
| 2017 |
A. Starukhin, V. Knyukshto, V. Plavskii, A. Gorski, J. Solarski Wavelength dependence of the efficiency of singlet oxygen generation upon photoexcitation of photosensitizers published pages: 2019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713202019 |
EPJ Web of Conferences 132 | 2019-09-02 |
| 2015 |
Ya.M.Dovbii, V.Ya.Chernii, I.M.Tretyakova, A.V.Gorski, A.S.Starukhin, S.V.Volkov SYNTHESIS OF DEHYDROACETIC ACID DERIVATIVES WITH CHROMOPHORICCHAINS AND THEIR COMPLEXES WITH ZIRCONIUM PHTHALOCYANINE published pages: 79-82, ISSN: 0041-6045, DOI: |
Ukrainian Chemistry Journal 12 | 2019-09-02 |
| 2017 |
V. Kovalska, S. Chernii, M. Losytskyy, J. Ostapko, I. Tretyakova, A. Gorski, V. Chernii, S. Yarmoluk Activity of Zn and Mg phthalocyanines and porphyrazines in amyloid aggregation of insulin published pages: e2660, ISSN: 0952-3499, DOI: 10.1002/jmr.2660 |
Journal of Molecular Recognition 30 August 2017 | 2019-09-02 |
| 2017 |
A. Starukhin, A. Gorski, V. Knyukshto, M. Kijak, I. Tretyakova, Y. Dovbii, V. Chernii Photophysical Features of Phthalocyanines Metallocomplexes with Out-of-Plane Ligands published pages: 109-114, ISSN: 2331-6535, DOI: 10.13189/ujpa.2017.110403 |
Universal Journal of Physics and Application 11/4 | 2019-09-02 |
| 2016 |
Vladyslava Kovalska, Svitlana Chernii, Mykhaylo Losytskyy, Yan Dovbii, Iryna Tretyakova, Rafal Czerwieniec, Victor Chernii, Sergiy Yarmoluk, Sergiy Volkov β-ketoenole dyes: Synthesis and study as fluorescent sensors for protein amyloid aggregates published pages: 274-281, ISSN: 0143-7208, DOI: 10.1016/j.dyepig.2016.04.053 |
Dyes and Pigments 132 | 2019-09-02 |
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