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Metallocomplexes of macrocyclic compounds for photonic devices

Total Cost €


EC-Contrib. €






 METCOPH project word cloud

Explore the words cloud of the METCOPH project. It provides you a very rough idea of what is the project "METCOPH" about.

groups    selective    temperatures    simultaneous    physical    investigation    sensing    consolidate    competence    optical    diverse    science    singlet    ideas    metallocomplexes    excitation    electrochemical    efforts    core    photophysical    basic    functional    respective    mentioned    rely    metals    steady    single    interdisciplinary    photonic    force    site    luminescence    resolution    atomic    transistor    microscopy    detection    engineering    complementary    lecs    expertise    incorporating    light    raman    characterisation    sensors    triplet    ambient    gained    cooperation    combines    objects    fabrication    solid    metcoph    switching    gathering    pulsed    transient    temperature    spectroscopic    multidisciplinary    mmc    quantum    newly    ligands    extended    mutual    mechanisms    oleds    ranging    cells    nanotechnology    compounds    countries    mmcs    technologies    driving    emitting    cw    lasers    involve    physics    manipulation    amplification    macrocyclic    absorption    transistors    photochemistry    scattering    fundamental    synthesized    chemistry    organic    spectroscopy    revealed    chemical    intensify   

Project "METCOPH" data sheet

The following table provides information about the project.


Organization address
address: KASPRZAKA 44/52
postcode: 1224

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Poland [PL]
 Project website
 Total cost 688˙500 €
 EC max contribution 688˙500 € (100%)
 Programme 1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge)
 Code Call H2020-MSCA-RISE-2014
 Funding Scheme MSCA-RISE
 Starting year 2015
 Duration (year-month-day) from 2015-01-01   to  2018-12-31


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
3    TEL AVIV UNIVERSITY IL (TEL AVIV) participant 81˙000.00
4    B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus BY (Minsk) partner 0.00
5    V.I.Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine UA (KYIV) partner 0.00


 Project objective

The key objective of the METCOPH multidisciplinary project is to intensify and consolidate cooperation between several research groups from member states and third countries on topics within the field of fundamental interdisciplinary science. The project combines the basic ideas of organic chemistry, solid state physics, photochemistry and spectroscopy of metallocomplexes of macrocyclic compounds (MMC) for applications in quantum information processing, sensing, switching and amplification. The project aims at focusing mutual efforts of five research groups with extended and complementary competence in their respective research fields and at gathering multidisciplinary and complementary expertise in chemical engineering and investigation of spectroscopy and photochemistry of MMCs for future design of photonic devices (e.g. organic light emitting devices – OLEDs, light emitting electrochemical cells – LECs, sensors, light emitting transistors) based on above mentioned compounds. The physical and chemical mechanisms of manipulation of optical response for these novel compounds will be revealed and analyzed with involving diverse spectroscopic approaches including steady-state and transient absorption, site-selective high-resolution luminescence, Raman scattering, atomic force microscopy and single-objects detection methods at different temperatures ranging from 1.2 K to ambient temperature. The expected results involve fabrication and chemical/photophysical characterisation of MMCs based on various core metals and incorporating various functional organic ligands. One of the key technologies will rely on driving optical transistor with CW and pulsed lasers and will make use of simultaneous excitation of singlet and triplet states of the metallocomplexes of macrocyclic compounds. The new information gained for these newly synthesized MMC systems will have impact on the engineering of novel functional MMCs for application in nanotechnology and photonic devices.


List of deliverables.
Progress Report II. Documents, reports 2019-09-02 13:50:58
Quantum-chemical calculations of the MMCs Documents, reports 2019-09-02 13:50:58
Scaling of properties of the single emitting MMCs Other 2019-09-02 13:50:58
Fluorescence and phosphorescence data Documents, reports 2019-09-02 13:50:57
Luminescent pincer complexes Documents, reports 2019-09-02 13:50:57
Vibrational assignment of investigated compounds Documents, reports 2019-09-02 13:50:57
Data of the conformational stability of the MMC Documents, reports 2019-09-02 13:50:57
A set of energy level diagrams describing the excitation energy deactivation channels in the case of MMCs Documents, reports 2019-09-02 13:50:57
MMCs with out-of-plane ligands Documents, reports 2019-09-02 13:50:57
Photostable luminescent MMCs Documents, reports 2019-09-02 13:50:57
Free-base organic core and cyclometalating ligands Documents, reports 2019-09-02 13:50:57
Progress Report I. Documents, reports 2019-09-02 13:50:57

Take a look to the deliverables list in detail:  detailed list of METCOPH deliverables.


year authors and title journal last update
List of publications.
2018 Aleksandr Starukhin, Aleksander Gorski, Michal Kijak
Influence of solid matrices on spectral features of metalloporphyrins
published pages: 3013, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819003013
EPJ Web of Conferences 190 2019-09-02
2018 Aleksandr Starukhin, Aleksander Gorski, Tatsiana Pavich, Valerii Kniukshto
Spectral features of conjugated bichromophores: porphyrins with curcumin
published pages: 4023, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004023
EPJ Web of Conferences 190 2019-09-02
2018 A. O. Savostianov, I. Yu. Eremchev, A. A. Gorshelev, A. V. Naumov, A. S. Starukhin
Wide-Range Spectral Diffusion in Single Mg-Tetraazaporphyrin Molecules in a Polymer Matrix at Cryogenic Temperatures
published pages: 406-411, ISSN: 0021-3640, DOI: 10.1134/s002136401807007x
JETP Letters 107/7 2019-09-02
2018 A. S. Starukhin, A. V. Gorski, M. Z. Kijak
Spectral Distortions of Metalloporphyrin Forms at Low Temperatures
published pages: 1560-1564, ISSN: 1062-8738, DOI: 10.3103/s1062873818120225
Bulletin of the Russian Academy of Sciences: Physics 82/12 2019-09-02
2018 Aleksandr Savostianov, Ivan Eremchev, Alexei Gorshelev, Sergei Orlov, Oleg Korotayev, Andrei Naumov, Aleksandr Starukhin
Structural and time-domain peculiarities of the fluorescence excitation spectra of single Mg-TAP in a polymer at low temperatures
published pages: 4019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004019
EPJ Web of Conferences 190 2019-09-02
2018 Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, Michał Kijak, Jędrzej Solarski, Alexander Semeikin, Tatjana Lyubimova
Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins
published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002
Journal of Photochemistry and Photobiology A: Chemistry 354 2019-09-02
2018 Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, Michał Kijak, Jędrzej Solarski, Alexander Semeikin, Tatjana Lyubimova
Temperature dependent steric hindrance effects in triplet state relaxation of meso -phenyl-substituted Pd-octaethylporphyrins
published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002
Journal of Photochemistry and Photobiology A: Chemistry 354 2019-09-02
2017 A. Starukhin, V. Knyukshto, A. Gorski, V. Chernii, I. Tretyakova, M. Kijak, P. Kowalska
Spectral manifestation of substitution of out-of-plane ligands in metallophtalocyanines
published pages: 3044, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713203044
EPJ Web of Conferences 132 2019-09-02
2017 Marsel Z. Shafikov, Alfiya F. Suleymanova, Rafał Czerwieniec, and Hartmut Yersin
Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough
published pages: , ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b05175
Chemistry of Materials 2019-09-02
2017 A. Gorski, A. Starukhin, S. Stavrov, S. Gawinkowski, J. Waluk
Resonance Raman spectroscopy study of protonated porphyrin
published pages: 350-355, ISSN: 1386-1425, DOI: 10.1016/j.saa.2016.09.038
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 173 2019-09-02
2016 Rafał Czerwieniec, Markus J. Leitl, Herbert H.H. Homeier, Hartmut Yersin
Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design
published pages: 2–28, ISSN: 0010-8545, DOI: 10.1016/j.ccr.2016.06.016
Coordination Chemistry Reviews 2019-09-02
2017 A. Starukhin, V. Knyukshto, V. Plavskii, A. Gorski, J. Solarski
Wavelength dependence of the efficiency of singlet oxygen generation upon photoexcitation of photosensitizers
published pages: 2019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713202019
EPJ Web of Conferences 132 2019-09-02
2015 Ya.M.Dovbii, V.Ya.Chernii, I.M.Tretyakova, A.V.Gorski, A.S.Starukhin, S.V.Volkov
published pages: 79-82, ISSN: 0041-6045, DOI:
Ukrainian Chemistry Journal 12 2019-09-02
2017 V. Kovalska, S. Chernii, M. Losytskyy, J. Ostapko, I. Tretyakova, A. Gorski, V. Chernii, S. Yarmoluk
Activity of Zn and Mg phthalocyanines and porphyrazines in amyloid aggregation of insulin
published pages: e2660, ISSN: 0952-3499, DOI: 10.1002/jmr.2660
Journal of Molecular Recognition 30 August 2017 2019-09-02
2017 A. Starukhin, A. Gorski, V. Knyukshto, M. Kijak, I. Tretyakova, Y. Dovbii, V. Chernii
Photophysical Features of Phthalocyanines Metallocomplexes with Out-of-Plane Ligands
published pages: 109-114, ISSN: 2331-6535, DOI: 10.13189/ujpa.2017.110403
Universal Journal of Physics and Application 11/4 2019-09-02
2016 Vladyslava Kovalska, Svitlana Chernii, Mykhaylo Losytskyy, Yan Dovbii, Iryna Tretyakova, Rafal Czerwieniec, Victor Chernii, Sergiy Yarmoluk, Sergiy Volkov
β-ketoenole dyes: Synthesis and study as fluorescent sensors for protein amyloid aggregates
published pages: 274-281, ISSN: 0143-7208, DOI: 10.1016/j.dyepig.2016.04.053
Dyes and Pigments 132 2019-09-02

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