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LiRichFCC SIGNED

A new class of powerful materials for electrochemical energy storage: Lithium-rich oxyfluorides with cubic dense packing

Total Cost €

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EC-Contrib. €

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Partnership

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Project "LiRichFCC" data sheet

The following table provides information about the project.

Coordinator
KARLSRUHER INSTITUT FUER TECHNOLOGIE 

Organization address
address: KAISERSTRASSE 12
city: KARLSRUHE
postcode: 76131
website: www.kit.edu

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Project website http://www.lirichfcc.eu
 Total cost 4˙114˙753 €
 EC max contribution 4˙114˙753 € (100%)
 Programme 1. H2020-EU.1.2.1. (FET Open)
 Code Call H2020-FETOPEN-2014-2015-RIA
 Funding Scheme RIA
 Starting year 2016
 Duration (year-month-day) from 2016-10-01   to  2019-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    KARLSRUHER INSTITUT FUER TECHNOLOGIE DE (KARLSRUHE) coordinator 1˙033˙152.00
2    UPPSALA UNIVERSITET SE (UPPSALA) participant 1˙166˙113.00
3    DANMARKS TEKNISKE UNIVERSITET DK (KGS LYNGBY) participant 739˙426.00
4    COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES FR (PARIS 15) participant 735˙851.00
5    KEMIJSKI INSTITUT SI (LJUBLJANA) participant 440˙210.00

Map

 Project objective

The LiRichFCC project will explore an entirely new class of materials for electrochemical energy storage termed “Li-rich FCC” comprising a very high concentration of lithium in a cubic dense packed structure (FCC). The process by which energy is stored in these materials constitutes a paradigm change in the design of battery materials and involves unexpected and surprisingly effective mechanisms: instead of storing lithium ions by intercalation into a stable host, lithium ions are populating and vacating lattice sites of the material itself. This new principle allows for unprecedented energy and power density compared to other battery materials and may revolutionize the use of batteries in applications involving a need for supplying large amounts of energy and power from small spaces. Li-rich FCC materials have just been discovered by one of the partners of the consortium, and the possible chemical compositions, properties, and charge storage principle associated with this new materials class are far from being understood. Thus, it is the aim of the project to explore and optimize possible compositions, synthesis methods, structural properties and dynamics of Li-rich FCC materials through an interdisciplinary approach involving predictive computational work, advanced chemical synthesis and high-end characterization. An important focus of the project will further be to evaluate the use of these materials for electrical energy storage and to identify potential other uses for Li-rich FCC materials that cannot be foreseen today. Due to the inherent paradigm change and the high promise Li-rich FCC materials hold both in regards to fundamental science as well as to battery applications, LiRichFCC fulfils all the preconditions of the call. The project is based on the long-term vision to develop a novel class of materials into practical use, involving foundational aspects in S&T with breakthrough character, high novelty and risk, and a broad, interdisciplinary approach.

 Deliverables

List of deliverables.
Workshop Websites, patent fillings, videos etc. 2020-04-03 12:16:35
Updated Data Management Plan Documents, reports 2020-04-03 12:16:58
Performance Report Documents, reports 2020-04-03 12:16:08
Synthesis Report Documents, reports 2020-04-03 12:18:42
Interim Coatings and Surfaces Report Documents, reports 2020-04-03 12:19:15
Bulk Transport Report Documents, reports 2020-04-03 12:14:56
Final Project Report Documents, reports 2020-04-03 12:17:22
Electrode Model Documents, reports 2020-04-03 12:15:45
Interface Transport Report Documents, reports 2020-04-03 12:15:22
Material Synthesis Other 2019-05-31 11:36:24
Dissemination Plan Documents, reports 2019-05-31 11:36:24
Data Management Plan Open Research Data Pilot 2019-05-31 11:36:20
Website Websites, patent fillings, videos etc. 2019-05-31 11:36:17

Take a look to the deliverables list in detail:  detailed list of LiRichFCC deliverables.

 Publications

year authors and title journal last update
List of publications.
2019 Ida Källquist, Andrew J. Naylor, Christian Baur, Johann Chable, Jolla Kullgren, Maximilian Fichtner, Kristina Edström, Daniel Brandell, Maria Hahlin
Degradation Mechanisms in Li 2 VO 2 F Li-Rich Disordered Rock-Salt Cathodes
published pages: 6084-6096, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b00829
Chemistry of Materials 31/16 2019-11-18
2019 Jin Hyun Chang, David Kleiven, Marko Melander, Jaakko Akola, Juan Maria Garcia-Lastra, Tejs Vegge
CLEASE: a versatile and user-friendly implementation of cluster expansion method
published pages: 325901, ISSN: 0953-8984, DOI: 10.1088/1361-648X/ab1bbc
Journal of Physics: Condensed Matter 31/32 2019-11-18
2018 Christian Baur, Johann Chable, Franziska Klein, Venkata Sai Kiran Chakravadhanula, Maximilian Fichtner
Reversible Delithiation of Disordered Rock Salt LiVO 2
published pages: 1484-1490, ISSN: 2196-0216, DOI: 10.1002/celc.201800189
ChemElectroChem 5/11 2019-11-18
2018 Musa Ali Cambaz, Bhaghavathi P. Vinayan, Holger Euchner, Rune E. Johnsen, Alexander A. Guda, Andrey Mazilkin, Yury V. Rusalev, Alexander L. Trigub, Axel Gross, Maximilian Fichtner
Design of Nickel-Based Cation-Disordered Rock-Salt Oxides: The Effect of Transition Metal (M = V, Ti, Zr) Substitution in LiNi 0.5 M 0.5 O 2 Binary Systems
published pages: 21957-21964, ISSN: 1944-8244, DOI: 10.1021/acsami.8b02266
ACS Applied Materials & Interfaces 10/26 2019-11-18
2019 Musa Ali Cambaz, Bhaghavathi P. Vinayan, Holger Euchner, Syed Atif Pervez, Holger Geßwein, Tobias Braun, Axel Gross, Maximilian Fichtner
Design and Tuning of the Electrochemical Properties of Vanadium-Based Cation-Disordered Rock-Salt Oxide Positive Electrode Material for Lithium-Ion Batteries
published pages: 39848-39858, ISSN: 1944-8244, DOI: 10.1021/acsami.9b12566
ACS Applied Materials & Interfaces 11/43 2019-11-18
2019 Musa Ali Cambaz, Bhaghavathi P. Vinayan, Holger Geßwein, Alexander Schiele, Angelina Sarapulova, Thomas Diemant, Andrey Mazilkin, Torsten Brezesinski, R. Jürgen Behm, Helmut Ehrenberg, Maximilian Fichtner
Oxygen Activity in Li-Rich Disordered Rock-Salt Oxide and the Influence of LiNbO 3 Surface Modification on the Electrochemical Performance
published pages: 4330-4340, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.8b04504
Chemistry of Materials 31/12 2019-11-18
2019 Musa Ali Cambaz, Bhaghavathi P. Vinayan, Syed Atif Pervez, Rune E. Johnsen, Holger Geßwein, Alexander A. Guda, Yury V. Rusalev, Michael Kiarie Kinyanjui, Ute Kaiser, Maximilian Fichtner
Suppressing Dissolution of Vanadium from Cation-Disordered Li 2– x VO 2 F via a Concentrated Electrolyte Approach
published pages: 7941-7950, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b02074
Chemistry of Materials 31/19 2019-11-18
2019 Christian Baur, Ida Källquist, Johann Chable, Jin Hyun Chang, Rune E. Johnsen, Francisco Ruiz-Zepeda, Jean-Marcel Ateba Mba, Andrew J. Naylor, Juan Maria Garcia-Lastra, Tejs Vegge, Franziska Klein, Annika R. Schür, Poul Norby, Kristina Edström, Maria Hahlin, Maximilian Fichtner
Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodes
published pages: 21244-21253, ISSN: 2050-7488, DOI: 10.1039/c9ta06291b
Journal of Materials Chemistry A 7/37 2019-11-18

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