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MULTI2HYCAT SIGNED

MULTI-site organic-inorganic HYbrid CATalysts for MULTI-step chemical processes

Total Cost €

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EC-Contrib. €

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Partnership

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 MULTI2HYCAT project word cloud

Explore the words cloud of the MULTI2HYCAT project. It provides you a very rough idea of what is the project "MULTI2HYCAT" about.

routes    innovative    catalysts    solid    attractive    replication    perfectly    industrial    promises    flexibility    strategy    selectivity    inorganic    sustainability    located    materials    prime    efficiency    proof    avoiding    view    isolation    competitiveness    economy    framework    pharmaceutical    organosiliceous    policies    catalytic    asymmetric    energetic    heterogeneous    pilot    validation    solvents    reducing    circular    specialty    carry    single    predominantly    reusable    class    resource    organic    hierarchically    elimination    subsequent    purification    environmental    catalysis    extra    gr    material    economic    sustainable    porous    wastes    preparation    efforts    mover    directives    efficient    structural    chemical    first    final    time    desired    active    versatility    solids    organocatalysts    conversions    reactor    conversion    intermediate    hierarchical    positions    points    90    sites    hybrid    multi2hycat    catalyst    obtain    upscale    demonstrated   

Project "MULTI2HYCAT" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITA DEGLI STUDI DEL PIEMONTE ORIENTALE AMEDEO AVOGADRO 

Organization address
address: DUOMO 6
city: VERCELLI
postcode: 13100
website: www.unipmn.it

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Italy [IT]
 Project website http://www.multi2hycat.eu
 Total cost 5˙346˙957 €
 EC max contribution 5˙346˙957 € (100%)
 Programme 1. H2020-EU.2.1.3. (INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials)
 Code Call H2020-NMBP-2016-two-stage
 Funding Scheme RIA
 Starting year 2017
 Duration (year-month-day) from 2017-01-01   to  2020-12-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITA DEGLI STUDI DEL PIEMONTE ORIENTALE AMEDEO AVOGADRO IT (VERCELLI) coordinator 963˙862.00
2    UNIVERSITY OF SOUTHAMPTON UK (SOUTHAMPTON) participant 854˙962.00
3    RHODIA OPERATIONS FR (PARIS) participant 808˙551.00
4    AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS ES (MADRID) participant 794˙050.00
5    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) participant 584˙531.00
6    ALMIRALL SA ES (BARCELONA) participant 518˙500.00
7    PNO CONSULTANTS GMBH DE (LEIPZIG) participant 475˙000.00
8    CAGE CHEMICALS SRL IT (NOVARA) participant 347˙500.00
9    SOLVAY SA BE (BRUXELLES) participant 0.00

Map

 Project objective

The main goal of MULTI2HYCAT is to design, obtain proof of concept (2 gr.) and upscale in a pre-pilot reactor (20-50 gr.) a new class of hierarchically-porous organic-inorganic hybrid materials, which will be used as active catalysts to carry out multi-step asymmetric catalytic processes with predominantly high conversions (up to 90%) and selectivity (in the range of 80-90%) towards the desired final products. The project promises to solve, for the first time, the low conversion and selectivity of current organosiliceous solids, while at the same time improving the flexibility and versatility and reducing costs of the obtained catalysts, making them attractive for a wide range of industrial applications. To this end, during the project, these novel catalysts will be demonstrated for specialty chemical and pharmaceutical applications, as a concrete prime-mover for subsequent replication. The MULTI2HYCAT project will contribute to the implementation of the EU policies and Directives on competitiveness and sustainability (e.g. Circular Economy Strategy and Resource Efficiency), through the validation of novel concepts in hybrid materials design for heterogeneous catalysis. This includes the preparation and validation of innovative hierarchical porous organic-inorganic materials with several active sites (organocatalysts) perfectly located in specific structural positions in their framework which will be used as single-solid reusable hybrid active catalyst to carry out multi-step catalytic processes. The new material will allow avoiding the extra-efforts associated with isolation of intermediate products, wastes and solvents elimination and purification processes thus enabling more efficient and sustainable catalytic routes from the economic, energetic as well as the environmental points of view.

 Deliverables

List of deliverables.
Dissemination activities report Open Research Data Pilot 2020-04-07 18:22:26
Web site Websites, patent fillings, videos etc. 2020-01-21 12:49:11

Take a look to the deliverables list in detail:  detailed list of MULTI2HYCAT deliverables.

 Publications

year authors and title journal last update
List of publications.
2018 Sebastián Llopis, Teresa García, Ángel Cantín, Alexandra Velty, Urbano Díaz, Avelino Corma
Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol
published pages: 5835-5847, ISSN: 2044-4753, DOI: 10.1039/c8cy01650j
Catalysis Science & Technology 8/22 2020-02-13
2019 José María Moreno, Alexandra Velty, Urbano Díaz, Avelino Corma
Synthesis of 2D and 3D MOFs with tuneable Lewis acidity from preformed 1D hybrid sub-domains
published pages: 2053-2066, ISSN: 2041-6520, DOI: 10.1039/c8sc04372h
Chemical Science 10/7 2020-02-13
2018 Sara Sáez-Ferre, Mercedes Boronat, Ángel Cantín, Fernando Rey, Pascual Oña-Burgos
Elucidation of the Interaction Mechanism between Organic Chiral Cages with Biomolecules through Nuclear Magnetic Resonance and Theoretical Studies
published pages: 16821-16829, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.8b05069
The Journal of Physical Chemistry C 122/29 2020-02-13
2019 Enrica Gianotti, Ivana Miletto, Chiara Ivaldi, Geo Paul, Leonardo Marchese, Marta Meazza, Ramon Rios, Robert Raja
Hybrid catalysts based on N-heterocyclic carbene anchored on hierarchical zeolites
published pages: 35336-35344, ISSN: 2046-2069, DOI: 10.1039/c9ra07516j
RSC Advances 9/61 2020-01-30
2019 Andrea Erigoni, Geo Paul, Marta Meazza, María Consuelo Hernández-Soto, Ivana Miletto, Ramon Rios, Candela Segarra, Leonardo Marchese, Robert Raja, Fernando Rey, Enrica Gianotti, Urbano Díaz
Acid properties of organosiliceous hybrid materials based on pendant (fluoro)aryl-sulfonic groups through a spectroscopic study with probe molecules
published pages: 6308-6317, ISSN: 2044-4753, DOI: 10.1039/c9cy01609k
Catalysis Science & Technology 9/22 2020-01-30
2019 Stephanie Chapman, Alexander J. O\'Malley, Ivana Miletto, Marina Carravetta, Paul Cox, Enrica Gianotti, Leonardo Marchese, Stewart F. Parker, Robert Raja
Integrated Theoretical and Empirical Studies for Probing Substrate–Framework Interactions in Hierarchical Catalysts
published pages: 9938-9947, ISSN: 0947-6539, DOI: 10.1002/chem.201901188
Chemistry – A European Journal 25/42 2020-01-30
2019 Chiara Ivaldi, Ivana Miletto, Geo Paul, Giovanni Giovenzana, Alberto Fraccarollo, Maurizio Cossi, Leonardo Marchese, Enrica Gianotti
Influence of Silicodactyly in the Preparation of Hybrid Materials
published pages: 848, ISSN: 1420-3049, DOI: 10.3390/molecules24050848
Molecules 24/5 2020-01-30
2018 Ivana Miletto, Alberto Fraccarollo, Nadia Barbero, Claudia Barolo, Maurizio Cossi, Leonardo Marchese, Enrica Gianotti
Mesoporous silica nanoparticles incorporating squaraine-based photosensitizers: a combined experimental and computational approach
published pages: 3038-3046, ISSN: 1477-9226, DOI: 10.1039/C7DT03735J
Dalton Transactions 47/9 2020-01-21
2017 Ivana Miletto, Geo Paul, Stephanie Chapman, Giorgio Gatti, Leonardo Marchese, Robert Raja, Enrica Gianotti
Mesoporous Silica Scaffolds as Precursor to Drive the Formation of Hierarchical SAPO-34 with Tunable Acid Properties
published pages: 9952-9961, ISSN: 0947-6539, DOI: 10.1002/chem.201701978
Chemistry - A European Journal 23/41 2020-01-21
2017 Alberto Fraccarollo, Lorenzo Canti, Leonardo Marchese, Maurizio Cossi
First principles study of 2D layered organohalide tin perovskites
published pages: 234703, ISSN: 0021-9606, DOI: 10.1063/1.4985054
The Journal of Chemical Physics 146/23 2020-01-21
2018 Alberto Fraccarollo, Leonardo Marchese, Maurizio Cossi
Ab Initio Design of Low Band Gap 2D Tin Organohalide Perovskites
published pages: 3677-3689, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.7b08928
The Journal of Physical Chemistry C 122/7 2020-01-21
2018 Ivana Miletto, Chiara Ivaldi, Geo Paul, Stephanie Chapman, Leonardo Marchese, Robert Raja, Enrica Gianotti
Hierarchical SAPO-34 Architectures with Tailored Acid Sites using Sustainable Sugar Templates
published pages: 297-301, ISSN: 2191-1363, DOI: 10.1002/open.201800001
ChemistryOpen 7/4 2020-01-21
2018 Sebastián Llopis, Teresa García, Ángel Cantín, Alexandra Velty, Urbano Díaz, Avelino Corma
Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol
published pages: 5835-5847, ISSN: 2044-4753, DOI: 10.1039/C8CY01650J
Catalysis Science & Technology 8/22 2020-01-21
2018 Geo Paul, Chiara Bisio, Ilaria Braschi, Maurizio Cossi, Giorgio Gatti, Enrica Gianotti, Leonardo Marchese
Combined solid-state NMR, FT-IR and computational studies on layered and porous materials
published pages: 5684-5739, ISSN: 0306-0012, DOI: 10.1039/c7cs00358g
Chemical Society Reviews 47/15 2020-01-21

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