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IonPEFC

Advanced catalyst electrodes from Ionic liquid modified PtNi nanowire arrays for PEFCs

Total Cost €

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EC-Contrib. €

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Partnership

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 IonPEFC project word cloud

Explore the words cloud of the IonPEFC project. It provides you a very rough idea of what is the project "IonPEFC" about.

automotive    solubility    conductivity    precious    life    effect    mainly    international    ptni    prepared    catalyst    stable    situ    structure    fuel    substantial    leaching    industrial    conventional    recent    cycles    ionpefc    annealing    driving    context    synthesis    relationships    pefc    enhancement    hydrophobic    difficulty    ils    il    protect    film    property    compare    material    single    metals    pure    nanowire    dissolution    super    gap    liquid    alloyed    ionic    pt    nanoparticle    chemistry    caused    improvements    stability    acid    involve    morphology    ni    synthesize    catalysts    washing    durability    nanowires    environment    surface    proton    performance    diffusivity    acidic    nanostructures    loading    thin    engineering    employing    ing    electrochemical    arrays    cell    post    oxygen    nonstructures    transitional    nanostructure    limit    modified    modify    electrodes    protic    area    unconventional    thermal    operation    extended    cells   

Project "IonPEFC" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
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surname: n.a.
function: n.a.
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 Coordinator Country United Kingdom [UK]
 Project website https://www.birmingham.ac.uk/research/activity/chemical-engineering/energy-chemical/fuel-cells/people/phd/Huixin-Zhang.aspx
 Total cost 195˙454 €
 EC max contribution 195˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-08-03   to  2019-08-02

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 195˙454.00

Map

 Project objective

Recent developments in PEFC research have seen a significant enhancement of catalyst activities and a reduction of cost at a reduced loading of precious metals by employing novel Pt-based extended surface area nanostructures alloyed with transitional metals, but the low stability caused by the easy dissolution of transitional metals in acidic PEFC environment, and the large difficulty to be integrated into devices due to the unconventional morphology of extended surface area nanostructures as Pt/C nanoparticle catalysts limit them mainly to pure material research, resulting in an increasing gap with real high performance devices.

IonPEFC will bring together the chemistry of nanostructure and ionic liquid (IL) synthesis with the engineering of fuel cells to develop PEFC electrodes with thin film catalyst nonstructures from PtNi nanowire arrays modified by protic ILs, targeting an improved understanding of structure-property relationships of electrodes to build high performance and robust PEFC devices. This will involve 4 research objectives: 1. To develop electrodes with thin film catalyst nanostructures from PtNi nanowire arrays based on the in-situ growing approach and to study the effect of post acid washing and annealing on the surface properties of PtNi nanowires. 2. To synthesize super hydrophobic, electrochemical and thermal stable ILs with high proton conductivity, oxygen solubility and diffusivity. The as-prepared ILs will be used to modify PtNi nanowire electrodes obtained to protect catalyst surface from Ni leaching in fuel cell operation. 3. To test in single cells the as-prepared and IL modified PtNi nanowire electrodes, and compare with conventional Pt/C electrodes. 4. To evaluate the long-term durability of the electrodes under real life-context at different European and international automotive driving cycles with the industrial partner.

It is expected that substantial performance and durability improvements will result from this research.

 Publications

year authors and title journal last update
List of publications.
2019 Min Wang, Huixin Zhang, Gnanavel Thirunavukkarasu, Ihtasham Salam, John R. Varcoe, Peter Mardle, Xiaoying Li, Shichun Mu, Shangfeng Du
Ionic Liquid-Modified Microporous ZnCoNC-Based Electrocatalysts for Polymer Electrolyte Fuel Cells
published pages: 2104-2110, ISSN: 2380-8195, DOI: 10.1021/acsenergylett.9b01407
ACS Energy Letters 4/9 2020-01-27
2019 Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du
Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel cells
published pages: , ISSN: 2095-0179, DOI: 10.1007/s11705-019-1838-8
Frontiers of Chemical Science and Engineering 2020-01-27

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