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XRayProton SIGNED

Ultrafast Structural Dynamics of Elementary Water-Mediated Proton Transport Processes

Total Cost €

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EC-Contrib. €

0

Partnership

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 XRayProton project word cloud

Explore the words cloud of the XRayProton project. It provides you a very rough idea of what is the project "XRayProton" about.

mechanisms    base    bridging    mediating    exchange    transport    transitions    accommodating    steady    electronic    resolved    acids    molecules    condensed    bases    acid    experiments    sources    solutions    infrared    probing    raised    water    chemistry    xas    elucidate    solution    harmonic    synchrotrons    table    poor    conversion    hydrated    absorption    monitor    species    visible    how    spectroscopy    shell    predominantly    transfer    time    aqueous    specificity    fuel    oxygen    evolution    proteins    proton    oxidation    pioneering    modern    react    mid    aromatic    structure    alcohols    unoccupied    solved    orbitals    cells    scales    limited    ray    protons    chemical    ultrafast    inner    resolving    dynamics    bulk    ultimately    laser    molecular    membrane    sequential    flatjet    amine    utilized    days    questions    shown    microscopic    decades    ultraviolet    bond    question    though    tool    structural    effort    hydrogen    liquid    elementary    carboxylic    picosecond    levels    neutralization    nature    ranges    femtosecond    trans    conjugate    soft    compounds    proceeds    elucidating    spectral   

Project "XRayProton" data sheet

The following table provides information about the project.

Coordinator
FORSCHUNGSVERBUND BERLIN EV 

Organization address
address: RUDOWER CHAUSSEE 17
city: BERLIN
postcode: 12489
website: www.fv-berlin.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 2˙482˙500 €
 EC max contribution 2˙482˙500 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2017-ADG
 Funding Scheme ERC-ADG
 Starting year 2018
 Duration (year-month-day) from 2018-09-01   to  2023-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FORSCHUNGSVERBUND BERLIN EV DE (BERLIN) coordinator 2˙482˙500.00

Map

 Project objective

How acids and bases react in water is a question raised since the pioneering days of modern chemistry. Recent decades have witnessed an increased effort in elucidating the microscopic mechanisms of proton exchange between acids and bases and the important mediating role of water in this. With ultrafast spectroscopy it has been shown that the elementary steps in aqueous proton transfer occur on femtosecond to picosecond time scales. Aqueous acid-base neutralization predominantly proceeds in a sequential way via water bridging acid and base molecules. These ultrafast experiments probing molecular transitions in the ultraviolet, visible and mid-infrared spectral ranges, though, only provide limited insight into the electronic structure of acids, bases and the water molecules accommodating the transfer of protons in the condensed phase. Soft-x-ray absorption spectroscopy (XAS), probing transitions from inner-shell levels to unoccupied molecular orbitals, is a tool to monitor electronic structure with chemical element specificity. The aim is now to develop steady-state and time-resolved soft-x-ray spectroscopy of acids and bases in water-poor and water-rich solutions. Here novel liquid flatjet technology is utilized with soft-x-ray sources at synchrotrons as well as table-top laser-based high-order harmonic systems, to elucidate the electronic structural evolution of proton transfer pathways. Questions to be solved are electronic structural changes upon hydrogen bond formation, the nature of hydrated proton species, and the impact of conversion from acid to conjugate base (or base to conjugate acid) in aromatic alcohols, carboxylic and amine compounds, and ultimately the oxygen oxidation state in hydrated protons. Resolving the electronic structural dynamics of elementary steps of aqueous proton transport will furthermore elucidate the role of mediating water in bulk solution, and in specific conditions such as hydrogen fuel cells or trans-membrane proteins.

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