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F-ELEMENT_ARCHITECT SIGNED

Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Total Cost €

0

EC-Contrib. €

0

Partnership

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 F-ELEMENT_ARCHITECT project word cloud

Explore the words cloud of the F-ELEMENT_ARCHITECT project. It provides you a very rough idea of what is the project "F-ELEMENT_ARCHITECT" about.

resonance    molecules    supporting    optimise    world    synthetic    architectures    exhibit    unusual    despite    optimal    synthesis    candidates    chemical    exist    axial    cycles    covalency    commercial    first    erc    liquid    electronic    prerequisite    helium    physical    temperatures    poorly    economy    lanthanide    ligand    quantum    single    lack    nitrogen    storage    cog    horizon    magnet    oxidation    trigonal    discovery    hysteresis    technologies    opening    transferable    criteria    effect    scientific    structure    attributes    space    thorough    textbook    nuclear    expensive    insights    whilst    stabilise    exploited    fresh    actinide    paramagnetic    reputation    fundamental    compounds    spectroscopy    magnetic    cooling    rare    complexes    issue    electron    2020    complementary    fuel    data    landmark    molecular    chemistry    unprecedented    astonishing    molecule    interactions    memory    equatorial    maximised    stabilisation    adventurous    pulsed    team    underpin    density    flagship    ideal   

Project "F-ELEMENT_ARCHITECT" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF MANCHESTER 

Organization address
address: OXFORD ROAD
city: MANCHESTER
postcode: M13 9PL
website: www.manchester.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 1˙990˙800 €
 EC max contribution 1˙990˙800 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2018-COG
 Funding Scheme ERC-COG
 Starting year 2019
 Duration (year-month-day) from 2019-09-01   to  2024-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF MANCHESTER UK (MANCHESTER) coordinator 1˙990˙800.00

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 Project objective

The astonishing properties of the f-elements have been exploited in numerous consumer technologies, despite their fundamental chemistry being poorly developed. It is now crucial to address this issue to provide the necessary insights to develop future applications. Design criteria exist to build f-element complexes with maximised physical attributes. This adventurous proposal targets the synthesis and thorough analysis of two complementary molecular f-element architectures that 1) optimise magnetic properties and 2) stabilise unusual oxidation states.

In Part 1, we target highly axial f-element complexes that lack equatorial ligand interactions. These molecules can exhibit maximised single-molecule magnet properties, including magnetic hysteresis, a memory effect and as a prerequisite of data storage, at liquid nitrogen temperatures. This is the necessary first step towards achieving high-density molecular data storage without expensive liquid helium cooling and future commercial applications.

In Part 2, we target trigonal f-element complexes that lack axial ligand interactions. These are optimal ligand fields for the stabilisation of low oxidation states, thus we aim for rare lanthanide/actinide(II) and unprecedented lanthanide/actinide(I) complexes. These compounds are ideal candidates for unique measurements of covalency by pulsed electron paramagnetic resonance spectroscopy, which will provide textbook data that can be transferable to nuclear fuel cycles.

An ERC CoG will provide the necessary resources to build a world-leading research team that will deliver landmark synthetic results and fresh insights into f-element electronic structure, whilst opening up new chemical space for future exploitation. These findings will underpin current technologies and will facilitate the discovery of future applications, supporting key Horizon 2020 priority areas including the Flagship on Quantum Technologies, and enhancing the scientific reputation and economy of the EU.

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