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F-ELEMENT_ARCHITECT SIGNED

Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Total Cost €

0

EC-Contrib. €

0

Partnership

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 F-ELEMENT_ARCHITECT project word cloud

Explore the words cloud of the F-ELEMENT_ARCHITECT project. It provides you a very rough idea of what is the project "F-ELEMENT_ARCHITECT" about.

synthetic    supporting    magnet    transferable    single    lanthanide    optimal    temperatures    equatorial    fresh    discovery    flagship    physical    covalency    effect    fuel    insights    cycles    horizon    economy    molecule    criteria    ideal    molecules    resonance    2020    interactions    trigonal    hysteresis    quantum    chemical    despite    issue    axial    stabilisation    pulsed    molecular    exhibit    poorly    electronic    rare    helium    unusual    reputation    electron    erc    world    compounds    storage    magnetic    complexes    spectroscopy    nuclear    structure    nitrogen    cog    chemistry    attributes    lack    fundamental    optimise    expensive    thorough    team    whilst    actinide    exist    adventurous    exploited    unprecedented    oxidation    synthesis    liquid    landmark    scientific    opening    candidates    underpin    commercial    memory    stabilise    technologies    paramagnetic    space    architectures    prerequisite    maximised    astonishing    data    textbook    cooling    first    ligand    complementary    density   

Project "F-ELEMENT_ARCHITECT" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF MANCHESTER 

Organization address
address: OXFORD ROAD
city: MANCHESTER
postcode: M13 9PL
website: www.manchester.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 1˙990˙800 €
 EC max contribution 1˙990˙800 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2018-COG
 Funding Scheme ERC-COG
 Starting year 2019
 Duration (year-month-day) from 2019-09-01   to  2024-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF MANCHESTER UK (MANCHESTER) coordinator 1˙990˙800.00

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 Project objective

The astonishing properties of the f-elements have been exploited in numerous consumer technologies, despite their fundamental chemistry being poorly developed. It is now crucial to address this issue to provide the necessary insights to develop future applications. Design criteria exist to build f-element complexes with maximised physical attributes. This adventurous proposal targets the synthesis and thorough analysis of two complementary molecular f-element architectures that 1) optimise magnetic properties and 2) stabilise unusual oxidation states.

In Part 1, we target highly axial f-element complexes that lack equatorial ligand interactions. These molecules can exhibit maximised single-molecule magnet properties, including magnetic hysteresis, a memory effect and as a prerequisite of data storage, at liquid nitrogen temperatures. This is the necessary first step towards achieving high-density molecular data storage without expensive liquid helium cooling and future commercial applications.

In Part 2, we target trigonal f-element complexes that lack axial ligand interactions. These are optimal ligand fields for the stabilisation of low oxidation states, thus we aim for rare lanthanide/actinide(II) and unprecedented lanthanide/actinide(I) complexes. These compounds are ideal candidates for unique measurements of covalency by pulsed electron paramagnetic resonance spectroscopy, which will provide textbook data that can be transferable to nuclear fuel cycles.

An ERC CoG will provide the necessary resources to build a world-leading research team that will deliver landmark synthetic results and fresh insights into f-element electronic structure, whilst opening up new chemical space for future exploitation. These findings will underpin current technologies and will facilitate the discovery of future applications, supporting key Horizon 2020 priority areas including the Flagship on Quantum Technologies, and enhancing the scientific reputation and economy of the EU.

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