Explore the words cloud of the OrganoMag project. It provides you a very rough idea of what is the project "OrganoMag" about.
The following table provides information about the project.
THE UNIVERSITY OF MANCHESTER
|Coordinator Country||United Kingdom [UK]|
|Total cost||183˙454 €|
|EC max contribution||183˙454 € (100%)|
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
|Duration (year-month-day)||from 2015-10-01 to 2017-09-30|
Take a look of project's partnership.
|1||THE UNIVERSITY OF MANCHESTER||UK (MANCHESTER)||coordinator||183˙454.00|
In this project, we will develop new single-molecule magnets (SMMs) that combine the strong magnetic anisotropy of lanthanide ions with a series of novel radical ligands. Highly unusual di- and tri-metallic Ln-SMMs are proposed in which the metals are bridged by radicals with heavy Group 15 donor atoms (i.e. the pnictogens, phosphorus-bismuth). The SMM field is dominated by systems with diamagnetic ligands: our radical ligands are novel, hence their applications in single-molecule magnetism will be unprecedented. We will exploit the rich electrochemistry of the proposed ligands: our DFT calculations show that the target heavy pnictogen radical anions have huge spin densities on the donor atoms, hence the diffuse unpaired spin of the radicals will provide a way of switching off the quantum tunnelling mechanisms that otherwise prevent hysteresis. Ultimately, this project introduces the potential for creating SMMs that show hysteresis at unprecedentedly high temperatures.
|year||authors and title||journal||last update|
Fu-Sheng Guo, Richard A. Layfield
Strong direct exchange coupling and single-molecule magnetism in indigo-bridged lanthanide dimers
published pages: 3130-3133, ISSN: 1359-7345, DOI: 10.1039/c7cc01046j
|Chemical Communications 53/21||2019-09-30|
Fu-Sheng Guo, Benjamin M. Day, Yan-Cong Chen, Ming-Liang Tong, Akseli MansikkamÃ¤ki, Richard A. Layfield
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
published pages: 11445-11449, ISSN: 1433-7851, DOI: 10.1002/anie.201705426
|Angewandte Chemie International Edition 56/38||2019-09-30|
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The information about "ORGANOMAG" are provided by the European Opendata Portal: CORDIS opendata.
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