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B-PhosphoChem SIGNED

Exploration of the 2D-Chemistry of Black Phosphorous

Total Cost €


EC-Contrib. €






 B-PhosphoChem project word cloud

Explore the words cloud of the B-PhosphoChem project. It provides you a very rough idea of what is the project "B-PhosphoChem" about.

chemical    considerably    phosphorus    nanostructures    transparency    constitute    book    elusive    give    classes    completely    supramolecular    characterizing    competence    physics    realm    successfully    practical    leadership    core    compound    combination    materials    chemistry    modulate    inorganic    physical    interface    systematic    solubility    group    sheets    interdisciplinary    tremendous    stabilization    constitutes    band    outstanding    discovered    organic    1d    2d    opportunity    chapter    desired    world    establishing    mobility    persistence    layer    class    located    synthetic    convinced    fundamental    gap    charge    packages    community    carrier    thin    tune    principles    close    combined    direction    reactivity    raised    synthesizing    bp    stable    calculations    performance    intercalation    documented    unexplored    orientation    compounds    basis    solid    scientific    ion    batteries    phosphochem    covalent    0d    predestinated    black    processability    fine    reveal   

Project "B-PhosphoChem" data sheet

The following table provides information about the project.


Organization address
postcode: 91054

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 2˙491˙250 €
 EC max contribution 2˙491˙250 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2016-ADG
 Funding Scheme ERC-ADG
 Starting year 2017
 Duration (year-month-day) from 2017-08-01   to  2022-07-31


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 


 Project objective

We propose the development of the chemistry of black phosphorus (BP). B-PhosphoChem will constitute a new text book chapter in the realm of synthetic chemistry located at the interface of inorganic-, organic-, and materials chemistry as well as solid state physics. B-PhosphoChem will provide the basis for exciting and so far elusive applications such as ion batteries and stable high performance devices. Thin sheets of BP represent a new class of 2D materials and have recently raised tremendous interest in the scientific community. Outstanding physical properties such as high charge carrier mobility, combined with transparency and the persistence of a band gap have been discovered. However, the chemistry of BP remains still unexplored. B-PhosphoChem will close this gap and will a) provide the opportunity to modulate and fine tune the physical properties, b) allow for considerably improving the processability and increasing the solubility, c) establish concepts for the desired chemical stabilization, d) give access to the combination of BP properties with those of other compound classes, e) reveal the fundamental chemical properties and reactivity principles, and f) provide methods for establishing practical applications. Five work packages will be addressed: 1) Production of Thin Layer BP, 2) Supramolecular Chemistry of BP, 3) Intercalation Compounds of BP, 4) Covalent Chemistry of BP, and 5) BP-Based Materials and Devices. The work packages will be supported by systematic calculations. For our group, whose core competence is synthetic organic and supramolecular chemistry, the orientation towards inorganic phosphorus chemistry constitutes a major step into a completely new direction. However, we are convinced to be the most predestinated research group in the world successfully facing this challenge because of our leadership and well documented interdisciplinary experience in synthesizing and characterizing 0D-, 1D-, and 2D nanostructures.


year authors and title journal last update
List of publications.
2019 Stefan Wild, Vicent Lloret, Victor Vega-Mayoral, Daniele Vella, Edurne Nuin, Martin Siebert, Maria Koleśnik-Gray, Mario Löffler, Karl J. J. Mayrhofer, Christoph Gadermaier, Vojislav Krstić, Frank Hauke, Gonzalo Abellán, Andreas Hirsch
Monolayer black phosphorus by sequential wet-chemical surface oxidation
published pages: 3570-3576, ISSN: 2046-2069, DOI: 10.1039/c8ra09069f
RSC Advances 9/7 2019-04-16
2017 Bence G. Márkus, Ferenc Simon, Károly Nagy, Titusz Fehér, Stefan Wild, Gonzalo Abellán, Julio C. Chacón-Torres, Andreas Hirsch, Frank Hauke
Electronic and Magnetic Properties of Black Phosphorus
published pages: 1700232, ISSN: 0370-1972, DOI: 10.1002/pssb.201700232
physica status solidi (b) 254/11 2019-04-16
2017 Gonzalo Abellán, Stefan Wild, Vicent Lloret, Nils Scheuschner, Roland Gillen, Udo Mundloch, Janina Maultzsch, Maria Varela, Frank Hauke, Andreas Hirsch
Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus
published pages: 10432-10440, ISSN: 0002-7863, DOI: 10.1021/jacs.7b04971
Journal of the American Chemical Society 139/30 2019-04-16
2018 Laura Meingast, Maria Koleśnik-Gray, Martin Siebert, Gonzalo Abellán, Stefan Wild, Vicent Lloret, Udo Mundloch, Frank Hauke, Andreas Hirsch, Vojislav Krstić
Effect of TCNQ Layer Cover on Oxidation Dynamics of Black Phosphorus
published pages: 1800179, ISSN: 1862-6254, DOI: 10.1002/pssr.201800179
physica status solidi (RRL) - Rapid Research Letters 12/8 2019-04-16
2018 Andreas Hirsch, Frank Hauke
Post-Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization
published pages: 4338-4354, ISSN: 1433-7851, DOI: 10.1002/anie.201708211
Angewandte Chemie International Edition 57/16 2019-04-16
2018 Bence G. Márkus, Gábor Csősz, Olivér Sági, Balázs Gyüre‐Garami, Vicent Lloret, Stefan Wild, Gonzalo Abellán, Norbert M. Nemes, Gyöngyi Klupp, Katalin Kamarás, Andreas Hirsch, Frank Hauke, Ferenc Simon
Electronic Properties of Air‐Sensitive Nanomaterials Probed with Microwave Impedance Measurements
published pages: 1800250, ISSN: 0370-1972, DOI: 10.1002/pssb.201800250
physica status solidi (b) 255/12 2019-04-16
2017 Gonzalo Abellán, Christian Neiss, Vicent Lloret, Stefan Wild, Julio C. Chacón-Torres, Katharina Werbach, Filippo Fedi, Hidetsugu Shiozawa, Andreas Görling, Herwig Peterlik, Thomas Pichler, Frank Hauke, Andreas Hirsch
Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals
published pages: 15267-15273, ISSN: 1433-7851, DOI: 10.1002/anie.201707462
Angewandte Chemie International Edition 56/48 2019-04-16
2019 Vicent Lloret, Miguel Ángel Rivero-Crespo, José Alejandro Vidal-Moya, Stefan Wild, Antonio Doménech-Carbó, Bettina S. J. Heller, Sunghwan Shin, Hans-Peter Steinrück, Florian Maier, Frank Hauke, Maria Varela, Andreas Hirsch, Antonio Leyva-Pérez, Gonzalo Abellán
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-018-08063-3
Nature Communications 10/1 2019-04-16

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