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Chiroptical, optical and magnetic probes for protein sensing based on cage metal complexes

Total Cost €


EC-Contrib. €






 CLATHROPROBES project word cloud

Explore the words cloud of the CLATHROPROBES project. It provides you a very rough idea of what is the project "CLATHROPROBES" about.

brings    scientists    synthesis    model    wp3    methodology    chiroptical    lacunar    diiminate    identification    cytotoxicity    pbmr    3d    structural    fluorescence    bioactivity    career    expertise    ideas    ir    participating    spatial    ineos    cage    sps    ua    sensing    fau    cd    wp1    epr    de    companies    reporting    probes    efficient    ru    training    scientific    clathroprobes    encapsulated    valuable    multidisciplinary    enhancement    discoveries    metal    ro    characterization    interactions    uwr    professional    nmr    reporters    countries    spectroscopic    luminescent    ligands    clathrochelate    collaborations    au    academia    industrial    industry    materials    ras    compounds    academic    ion    clathrochelates    chemical    tris    vis    pl    pair    efforts    six    young    itc    social    devoted    uv    complexes    network    excellence    biomolecules    univie    complete    molecular    innovative    transfer    representing    science    biological    sectors    successful    joint    wp2    complementary   

Project "CLATHROPROBES" data sheet

The following table provides information about the project.


Organization address
postcode: 50137

contact info
title: n.a.
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surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Poland [PL]
 Total cost 958˙500 €
 EC max contribution 796˙500 € (83%)
 Programme 1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge)
 Code Call H2020-MSCA-RISE-2017
 Funding Scheme MSCA-RISE
 Starting year 2018
 Duration (year-month-day) from 2018-01-01   to  2021-12-31


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIWERSYTET WROCLAWSKI PL (WROCLAW) coordinator 148˙500.00
3    SARA PHARM SOLUTIONS SRL RO (BUCURESTI) participant 144˙000.00
4    UNIVERSITAT WIEN AT (WIEN) participant 103˙500.00


 Project objective

The CLATHROPROBES project is devoted to the design and development of novel, highly efficient chiroptical, luminescent, IR, NMR and EPR probes for sensing and structural studies of biomolecules based on cage metal complexes (clathrochelates and lacunar complexes of spatial tris-diiminate ligands with encapsulated 3d-metal ion) as molecular reporters. For successful design and synthesis of cage metal complexes (WP1), their complete structural and spectroscopic characterization (WP2), studies of their interactions with biomolecules and reporting properties, and their cytotoxicity and bioactivity in model systems (WP3), the project brings together researchers from four academic institutions and two industrial companies, representing six countries (PL, DE, UA, RU, RO, AU). The participants will contribute to the project with different, highly specific, yet complementary expertise, namely in chemical synthesis of clathrochelate complexes (PBMR, INEOS RAS, FAU), identification and structural studies of compounds and materials (PBMR, INEOS RAS, FAU, UWR, UNIVIE, SPS), characterization of interactions between ligands/clathrochelates/materials and biomolecules by CD, UV-VIS, fluorescence ITC, (UWR, FAU, PBMR, UNIVIE, SPS), IR, NMR (INEOS RAS) methodology, and biological studies (FAU). Joint efforts of participants of this multidisciplinary project will provide - the transfer of knowledge between scientists of different research areas, sectors and countries that will enhance level of their professional scientific/technical expertise, -training of young researchers, very important for their further scientific success or industrial career, - enhancement of research activity and network of participating Institutions, - new long-term collaborations between the partners, - increase of academia-industry interactions, so valuable for innovative ideas and discoveries, and pair scientific excellence with social awareness and understanding of current tasks and problems of science.


List of deliverables.
Internet website of the project Websites, patent fillings, videos etc. 2019-05-17 09:31:41

Take a look to the deliverables list in detail:  detailed list of CLATHROPROBES deliverables.


year authors and title journal last update
List of publications.
2019 Roman A. Selin, Nina V. Chornenka, Viktor Ya. Chernii, Andriy Mokhir, Anna V. Vologzhanina, Alexander S. Belov, Alexander L. Pomadchik, Yan Z. Voloshin
Chemical design of the heterodifunctionalized iron(II) clathrochelates with terminal biorelevant carboxyl group and reactive triple C≡C bond: Synthesis, structure, redox properties and their stability in various media
published pages: 119047, ISSN: 0020-1693, DOI: 10.1016/j.ica.2019.119047
Inorganica Chimica Acta 496 2020-02-13
2019 Sergii I. Shylin, Mariia V. Pavliuk, Luca D’Amario, Igor O. Fritsky, Gustav Berggren
Photoinduced hole transfer from tris(bipyridine)ruthenium dye to a high-valent iron-based water oxidation catalyst
published pages: 162-174, ISSN: 1359-6640, DOI: 10.1039/c8fd00167g
Faraday Discussions 215 2020-02-13
2019 Svetlana A. Belova (Savkina), Semyon V. Dudkin, Alexander S. Belov, Yulia V. Nelyubina, Valentin V. Novikov, Yan V. Zubavichus, Yan Z. Voloshin
Pseudomacrobicyclic Phthalocyaninate-Capped Cobalt(III) tris-Pyridineoximates: Template Synthesis, X-Ray Structure and Spectral Characteristics
published pages: 193-197, ISSN: 1998-9539, DOI: 10.6060/mhc190550d
Macroheterocycles 12/2 2020-02-13
2019 Vladyslava Kovalska, Serhii Vakarov, Mykhaylo Losytskyy, Marina Kuperman, Nina Chornenka, Yuliya Toporivska, Elzbieta Gumienna-Kontecka, Yan Voloshin, Oleg Varzatskii, Andriy Mokhir
Dicarboxyl-terminated iron( ii ) clathrochelates as ICD-reporters for globular proteins
published pages: 24218-24230, ISSN: 2046-2069, DOI: 10.1039/c9ra04102h
RSC Advances 9/42 2020-02-13
2019 Vladyslava Kovalska, Marina Kuperman, Mykhaylo Losytskyy, Serhii Vakarov, Slawomir Potocki, Sergiy Yarmoluk, Yan Voloshin, Oleg Varzatskii, Elzbieta Gumienna-Kontecka
Induced CD of iron( ii ) clathrochelates: sensing of the structural and conformational alterations of serum albumins
published pages: 338-348, ISSN: 1756-5901, DOI: 10.1039/c8mt00278a
Metallomics 11/2 2019-10-08
2019 Sergii I. Shylin, Mariia V. Pavliuk, Luca D’Amario, Fikret Mamedov, Jacinto Sá, Gustav Berggren, Igor O. Fritsky
Efficient visible light-driven water oxidation catalysed by an iron( iv ) clathrochelate complex
published pages: 3335-3338, ISSN: 1359-7345, DOI: 10.1039/c9cc00229d
Chemical Communications 55/23 2019-10-08
2018 Vladyslava B. Kovalska, Serhii V. Vakarov, Marina V. Kuperman, Mykhaylo Y. Losytskyy, Elzbieta Gumienna-Kontecka, Yan Z. Voloshin, Oleg A. Varzatskii
Induced chirality of cage metal complexes switched by their supramolecular and covalent binding
published pages: 1036-1052, ISSN: 1477-9226, DOI: 10.1039/c7dt03731g
Dalton Transactions 47/4 2019-06-11
2018 Genrikh E. Zelinskii, Alexander S. Belov, Irina G. Belaya, Anna V. Vologzhanina, Valentin V. Novikov, Oleg A. Varzatskii, Yan Z. Voloshin
The molecular design of cage metal complexes for biological applications: pathways of the synthesis, and X-ray structures of a series of new N 2 -, S 2 - and O 2 -alicyclic iron( ii ) di- and tetrachloroclathrochelates
published pages: 56-66, ISSN: 1144-0546, DOI: 10.1039/c7nj03051g
New Journal of Chemistry 42/1 2019-05-17
2018 Yan Z. Voloshin, Valentin V. Novikov, Yulia V. Nelyubina, Alexander S. Belov, Dmitrii M. Roitershtein, Anton Savitsky, Andriy Mokhir, Jörg Sutter, Matthias E. Miehlich, Karsten Meyer
Synthesis and characterization of an Fe( i ) cage complex with high stability towards strong H-acids
published pages: 3436-3439, ISSN: 1359-7345, DOI: 10.1039/c7cc09611a
Chemical Communications 54/28 2019-05-17
2018 Alexander A. Pavlov, Svetlana A. Savkina, Alexander S. Belov, Yan Z. Voloshin, Yulia V. Nelyubina, Valentin V. Novikov
Very Large Magnetic Anisotropy of Cage Cobalt(II) Complexes with a Rigid Cholesteryl Substituent from Paramagnetic NMR Spectroscopy
published pages: 4941-4946, ISSN: 2470-1343, DOI: 10.1021/acsomega.8b00772
ACS Omega 3/5 2019-05-17
2018 Irina N. Denisenko, Oleg A. Varzatskii, Roman A. Selin, Alexander S. Belov, Ekaterina G. Lebed, Anna V. Vologzhanina, Yan V. Zubavichus, Yan Z. Voloshin
Extension and functionalization of an encapsulating macrobicyclic ligand using palladium-catalyzed Suzuki–Miyaura and Sonogashira reactions of iron( ii ) dihalogenoclathrochelates with inherent halogen substituents
published pages: 13578-13587, ISSN: 2046-2069, DOI: 10.1039/c8ra01819g
RSC Advances 8/24 2019-05-17
2018 Viktor Reshetnikov, Jonas Hahn, Christian Maueröder, Christine Czegley, Luis Enrique Munoz, Martin Herrmann, Markus H. Hoffmann, Andriy Mokhir
Chemical Tools for Targeted Amplification of Reactive Oxygen Species in Neutrophils
published pages: 1827, ISSN: 1664-3224, DOI: 10.3389/fimmu.2018.01827
Frontiers in Immunology 9 2019-05-17

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