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CoopCat SIGNED

Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts

Total Cost €

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EC-Contrib. €

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Partnership

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 CoopCat project word cloud

Explore the words cloud of the CoopCat project. It provides you a very rough idea of what is the project "CoopCat" about.

clusters    molecular    materials    lay    energy    efficiency    heavier    cooperative    versatile    clear    healthcare    manufacturing    reactions    ground    multidisciplinary    broad    compounds    hybrid    heart    combine    economy    original    delivering    unreactive    strategies    synthetic    valent    transition    critical    rely    combining    discovering    direct    dependant    intercluster    scope    generation    sustainable    green    lewis    science    minimize    breaking    tm    frustrated    chemical    homogeneous    metal    environmental    quality    bricks    sustainability    catalytic    inform    catalysts    least    transformations    chemistry    group    innovative    benefits    foundation    iccs    life    solar    complementary    substrates    erc    feasibility    catalysis    cooperation    metals    otherwise    independent    fundamental    mg    activation    pioneering    innovations    flps    catalyst    mgs    polymetallic    industrial    technologies    gained    icc    ranging    nanoscale    heterogeneous    pairs    anthropogenic    heterogeneized    pivotal    interdisciplinary   

Project "CoopCat" data sheet

The following table provides information about the project.

Coordinator
AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS 

Organization address
address: CALLE SERRANO 117
city: MADRID
postcode: 28006
website: http://www.csic.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Project website http://jcamposgroup.iiq.us-csic.es/
 Total cost 1˙445˙000 €
 EC max contribution 1˙445˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2017-STG
 Funding Scheme ERC-STG
 Starting year 2018
 Duration (year-month-day) from 2018-02-01   to  2023-01-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS ES (MADRID) coordinator 1˙445˙000.00

Map

 Project objective

Catalysis, a multidisciplinary science at the heart of many industrial processes, is crucial to deliver future growth and minimize anthropogenic environmental impact, thus being critical to our quality of life. Thus, the development and fundamental understanding of innovative new catalyst systems has clear, direct and long-term benefits to the chemical manufacturing sector and to the broader knowledge-based economy. In this ERC project I will develop novel innovative cooperative catalysts using interdisciplinary chemical systems based on main group elements, transition metals and molecular clusters to achieve better efficiency and improve chemical scope and sustainability of key chemical transformations. This will be achieved through 3 complementary and original strategies based on catalytic cooperation: (i) Transition-Metal Frustrated Lewis Pairs (TM-FLPs); (ii) hybrid systems combining low-valent heavier main group elements with transition metals (Hybrid TM/MGs); and (iii) intercluster compounds (ICCs) as versatile heterogeneized materials for Green Catalysis. These systems, of high synthetic feasibility, combine fundamental concepts from independent areas, e.g. FLPs and low-valent heavier main group elements with transition metal chemistry, and homogeneous with heterogeneous catalysis. The overall approach will be pivotal in discovering novel reactions that rely on the activation of otherwise unreactive substrates. The experience and knowledge gained from (i)-(iii) will be used to inform the design of a second generation of ICC materials in which at least one of the nanoscale bricks is based on polymetallic TM-FLPs or Hybrid TM/MG systems. Delivering ground-breaking new fundamental science, this pioneering project will lay the foundation for future broad ranging benefits to a number of EU priority areas dependant on innovations in catalysis: innovative and sustainable future energy systems, solar technologies, sustainable chemistry, manufacturing, and healthcare.

 Publications

year authors and title journal last update
List of publications.
2018 Marina Pérez-Jiménez, Jesús Campos, Joaquín López-Serrano, Ernesto Carmona
Reactivity of a trans -[H–MoMo–H] unit towards alkenes and alkynes: bimetallic migratory insertion, H-elimination and other reactions
published pages: 9186-9189, ISSN: 1359-7345, DOI: 10.1039/c8cc04945a
Chemical Communications 54/66 2019-08-30
2019 Nereida Hidalgo, Celia Maya, Jesús Campos
Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag( i ) metal-only Lewis pair
published pages: , ISSN: 1359-7345, DOI: 10.1039/c9cc03008e
Chemical Communications 2019-09-02
2019 Nereida Hidalgo, Sonia Bajo, Juan José Moreno, Carlos Navarro-Gilabert, Brandon Q. Mercado, Jesús Campos
Reactivity of a gold( i )/platinum(0) frustrated Lewis pair with germanium and tin dihalides
published pages: 9127-9138, ISSN: 1477-9226, DOI: 10.1039/c9dt00702d
Dalton Transactions 48/25 2019-09-02
2019 Juan J. Moreno, María F. Espada, Jesús Campos, Joaquín López-Serrano, Stuart A. Macgregor, Ernesto Carmona
Base-Promoted, Remote C–H Activation at a Cationic (η 5 -C 5 Me 5 )Ir(III) Center Involving Reversible C–C Bond Formation of Bound C 5 Me 5
published pages: 2205-2210, ISSN: 0002-7863, DOI: 10.1021/jacs.8b11752
Journal of the American Chemical Society 141/6 2019-06-03

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