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LIDOS SIGNED

Light-Induced Spin Switch using Dynamic Organic Species

Total Cost €

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EC-Contrib. €

0

Partnership

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 LIDOS project word cloud

Explore the words cloud of the LIDOS project. It provides you a very rough idea of what is the project "LIDOS" about.

covalent    serve    hosting    designed    intersection    verdazyl    explore    diarylethene    uses    switches    dyads    unpaired    interaction    overarching    first    techniques    underexplored    molecules    dft    choreography    photochemistry    undergoing    reversible    identification    modulates    interactions    primary    radical    strategy    elusive    combines    combinations    tuned    host    supramolecular    molecular    derivatives    principles    components    temperature    azobenzene    technological    transition    optimize    moiety    primarily    photoswitches    alter    mission    adjacent    magnetic    candidates    photoswitch    combine    understand    light    despite    attempts    physical    switch    silico    obtain    linker    screening    pronounced    optical    electrons    efficient    describe    pm    enhanced    groups    lidos    computational    irradiation    sized    room    epfl    lies    photochemical    follows    visible    units    rationally    structural    moieties    chemistry    nanometer    photomagnetic    metals    featuring    dta    magnetism    purely    employing    myriad    radicals    affixed    organic    triggered    dynamics   

Project "LIDOS" data sheet

The following table provides information about the project.

Coordinator
ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE 

Organization address
address: BATIMENT CE 3316 STATION 1
city: LAUSANNE
postcode: 1015
website: www.epfl.ch

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Switzerland [CH]
 Total cost 175˙419 €
 EC max contribution 175˙419 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-10-01   to  2020-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE CH (LAUSANNE) coordinator 175˙419.00

Map

 Project objective

The LIDOS project uses in-silico approaches to design nanometer sized photomagnetic (PM) switches. Switches of this kind find use in myriad technological devices, primarily because of their ability to alter their magnetic response upon light irradiation. This project follows an underexplored, yet promising, strategy to obtain new PM switches with enhanced properties. Specifically, dyads (i.e. two-component molecules) will be designed that combine a photoswitch and a magnetic moiety hosting unpaired electrons. Despite attempts to design PM switches employing both transition metals and purely-organic radicals as magnetic units, significant advances in magnetic response remain elusive. This project aims to rationally develop efficient PM switches featuring pronounced changes in magnetic response at room temperature, using purely-organic components. Azobenzene and Diarylethene derivatives will serve as photoswitches, whose primary mission is undergoing a reversible structural change that modulates the magnetic interaction between the radical moieties of adjacent dyads. Thus, the design principles are based on supramolecular choreography. DTA- and Verdazyl- molecules will be targeted as radicals, and will be affixed to photoswitches via linker groups. In the first step, computational screening will be used to explore the best component combinations leading to a set of potential PM switches. In the second step, candidates will be further tuned to optimize their optical properties. The overarching goal is the identification of a reversible PM switch triggered by visible light.

LIDOS lies at the intersection of photochemistry, molecular magnetism, computational chemistry, and physical organic chemistry. It combines well-established DFT-based approaches, computational methods to describe and understand non-covalent interactions recently developed at the host institution (EPFL), and state-of-the-art molecular dynamics techniques to study the photochemical process.

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The information about "LIDOS" are provided by the European Opendata Portal: CORDIS opendata.

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