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LIDOS SIGNED

Light-Induced Spin Switch using Dynamic Organic Species

Total Cost €

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EC-Contrib. €

0

Partnership

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 LIDOS project word cloud

Explore the words cloud of the LIDOS project. It provides you a very rough idea of what is the project "LIDOS" about.

lidos    physical    irradiation    pm    unpaired    hosting    photoswitch    lies    chemistry    screening    obtain    attempts    intersection    understand    interaction    employing    combine    verdazyl    dft    triggered    dynamics    dyads    optimize    combines    room    despite    host    primarily    molecular    strategy    photoswitches    choreography    moieties    pronounced    sized    organic    azobenzene    undergoing    enhanced    adjacent    tuned    radicals    elusive    modulates    primary    interactions    groups    photochemistry    reversible    photomagnetic    technological    optical    techniques    visible    electrons    supramolecular    temperature    uses    designed    underexplored    linker    silico    switches    transition    identification    nanometer    metals    dta    molecules    magnetic    moiety    efficient    candidates    follows    serve    first    photochemical    radical    featuring    computational    explore    covalent    units    light    magnetism    derivatives    diarylethene    myriad    combinations    mission    structural    affixed    components    epfl    overarching    switch    rationally    principles    alter    purely    describe   

Project "LIDOS" data sheet

The following table provides information about the project.

Coordinator
ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE 

Organization address
address: BATIMENT CE 3316 STATION 1
city: LAUSANNE
postcode: 1015
website: www.epfl.ch

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Switzerland [CH]
 Total cost 175˙419 €
 EC max contribution 175˙419 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-10-01   to  2020-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE CH (LAUSANNE) coordinator 175˙419.00

Map

 Project objective

The LIDOS project uses in-silico approaches to design nanometer sized photomagnetic (PM) switches. Switches of this kind find use in myriad technological devices, primarily because of their ability to alter their magnetic response upon light irradiation. This project follows an underexplored, yet promising, strategy to obtain new PM switches with enhanced properties. Specifically, dyads (i.e. two-component molecules) will be designed that combine a photoswitch and a magnetic moiety hosting unpaired electrons. Despite attempts to design PM switches employing both transition metals and purely-organic radicals as magnetic units, significant advances in magnetic response remain elusive. This project aims to rationally develop efficient PM switches featuring pronounced changes in magnetic response at room temperature, using purely-organic components. Azobenzene and Diarylethene derivatives will serve as photoswitches, whose primary mission is undergoing a reversible structural change that modulates the magnetic interaction between the radical moieties of adjacent dyads. Thus, the design principles are based on supramolecular choreography. DTA- and Verdazyl- molecules will be targeted as radicals, and will be affixed to photoswitches via linker groups. In the first step, computational screening will be used to explore the best component combinations leading to a set of potential PM switches. In the second step, candidates will be further tuned to optimize their optical properties. The overarching goal is the identification of a reversible PM switch triggered by visible light.

LIDOS lies at the intersection of photochemistry, molecular magnetism, computational chemistry, and physical organic chemistry. It combines well-established DFT-based approaches, computational methods to describe and understand non-covalent interactions recently developed at the host institution (EPFL), and state-of-the-art molecular dynamics techniques to study the photochemical process.

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The information about "LIDOS" are provided by the European Opendata Portal: CORDIS opendata.

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