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Molecule-induced control over 2D Materials

Total Cost €


EC-Contrib. €






Project "Mol-2D" data sheet

The following table provides information about the project.


Organization address
postcode: 46010

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 2˙499˙950 €
 EC max contribution 2˙499˙950 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2017-ADG
 Funding Scheme ERC-ADG
 Starting year 2018
 Duration (year-month-day) from 2018-10-01   to  2023-09-30


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE VALENCIA ES (VALENCIA) coordinator 2˙499˙950.00


 Project objective

We propose to create heterostructures based on functional molecules and 2D materials. As molecular systems we focus on bistable magnetic molecules able to switch between two spin states upon the application of an external stimulus (temperature, light, pressure, electric field etc.). As 2D materials we concentrate on those exhibiting in particular superconductivity or magnetism. The driving idea is to tune/improve the properties of the “all surface” 2D material via an active control of the hybrid interface. This concept, which goes much beyond the conventional chemical functionalization of a 2D material, will provide an entire new class of smart molecular/2D heterostructures, which may be at the origin of a novel generation of hybrid materials and devices of direct application in highly topical fields like electronics, spintronics, molecular sensing and energy storage. Through this molecular approach, we will address major challenges in different areas of the 2D research: i) in 2D physics, we investigate the new properties that should appear in heterostructures involving 2D superconductors and 2D magnets or magnetic molecules; ii) in 2D electronics, we explore the possibility of tuning the superconducting/magnetic properties of a 2D material by applying an external stimulus (light for example), or to design smart electronic/spintronic devices able to respond to physical (light, magnetic field, etc.) or chemical stimuli (trapping of molecules); iii) in 2D composite materials, a general goal is to design hybrid molecular/2D materials with improved properties with respect to the pure 2D material to be used in the fabrication of energy storage devices. To reach these challenging goals an integrative and multidisciplinary approach is proposed in which various facets of chemistry – coordination, solid-state and supramolecular chemistry – are coupled with physics, materials science and nanotechnology.


year authors and title journal last update
List of publications.
2020 Luis Escalera-Moreno, José J. Baldoví, Alejandro Gaita-Ariño, Eugenio Coronado
Design of high-temperature f -block molecular nanomagnets through the control of vibration-induced spin relaxation
published pages: 1593-1598, ISSN: 2041-6520, DOI: 10.1039/c9sc03133b
Chemical Science 11/6 2020-04-07
2020 Jorge Romero, Maria Varela, Mhamed Assebban, Víctor Oestreicher, Alejandra Guedeja-Marrón, Jose L. Jorda, Gonzalo Abellán, Eugenio Coronado
Insights into the formation of metal carbon nanocomposites using hybrid NiFe layered double hydroxides as precursors
published pages: , ISSN: 2041-6520, DOI: 10.1039/d0sc00697a
Chemical Science 2020-04-07
2019 Romain Grasset, Yann Gallais, Alain Sacuto, Maximilien Cazayous, Samuel Mañas-Valero, Eugenio Coronado, Marie-Aude Méasson
Pressure-Induced Collapse of the Charge Density Wave and Higgs Mode Visibility in 2 H − TaS 2
published pages: 127001 (6), ISSN: 0031-9007, DOI: 10.1103/PhysRevLett.122.127001
Physical Review Letters 122/12 2020-04-07
2019 Víctor García-López, Mario Palacios-Corella, Salvador Cardona-Serra, Miguel Clemente-León, Eugenio Coronado
Spin-crossover iron( ii ) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T (LIESST) of 120 K
published pages: 12227-12230, ISSN: 1359-7345, DOI: 10.1039/c9cc05988a
Chemical Communications 55/81 2020-04-01
2019 R. Torres-Cavanillas, L. Lima-Moya, F. D. Tichelaar, H. W. Zandbergen, M. Giménez-Marqués, E. Coronado
Downsizing of robust Fe-triazole@SiO 2 spin-crossover nanoparticles with ultrathin shells
published pages: 15465-15469, ISSN: 1477-9226, DOI: 10.1039/c9dt02086a
Dalton Transactions 48/41 2020-04-01
2019 Jorge Romero, Helena Prima‐Garcia, Maria Varela, Sara G. Miralles, Víctor Oestreicher, Gonzalo Abellán, Eugenio Coronado
Giant Enhancement in the Supercapacitance of NiFe–Graphene Nanocomposites Induced by a Magnetic Field
published pages: 1900189, ISSN: 0935-9648, DOI: 10.1002/adma.201900189
Advanced Materials 31/28 2020-04-01
2020 Jose A. Carrasco, Alvaro Seijas Da Silva, Víctor Oestreicher, Jorge Romero, Bence G. Márkus, Ferenc Simon, Bruno J. C. Vieira, João C. Waerenborgh, Gonzalo Abellán, Eugenio Coronado
Fundamental Insights into the Covalent Silane Functionalization of NiFe‐Layered Double Hydroxides
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201905397
Chemistry – A European Journal 2020-04-01
2019 V. García-López, M. Palacios-Corella, M. Clemente-León, E. Coronado
Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl position
published pages: 95-100, ISSN: 0277-5387, DOI: 10.1016/j.poly.2019.05.029
Polyhedron 170 2020-04-01
2019 Marta Galbiati, Sergio Tatay, Simon M.-M. Dubois, Florian Godel, Regina Galceran, Samuel Mañas-Valero, Maëlis Piquemal-Banci, Aymeric Vecchiola, Jean-Christophe Charlier, Alicia Forment-Aliaga, Eugenio Coronado, Bruno Dlubak, Pierre Seneor
Path to Overcome Material and Fundamental Obstacles in Spin Valves Based on Mo S 2 and Other Transition-Metal Dichalcogenides
published pages: , ISSN: 2331-7019, DOI: 10.1103/physrevapplied.12.044022
Physical Review Applied 12/4 2020-04-01
2018 J. López-Cabrelles, S. Mañas-Valero, I. J. Vitórica-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado
Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
published pages: 1001-1007, ISSN: 1755-4330, DOI: 10.1038/s41557-018-0113-9
Nature Chemistry 10/10 2020-04-01
2018 Jose A. Carrasco, Roger Sanchis-Gual, Alvaro Seijas-Da Silva, Gonzalo Abellán, Eugenio Coronado
Influence of the Interlayer Space on the Water Oxidation Performance in a Family of Surfactant-Intercalated NiFe-Layered Double Hydroxides
published pages: 6798-6807, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b01263
Chemistry of Materials 31/17 2020-04-01
2020 Eugenio Coronado
Molecular magnetism: from chemical design to spin control in molecules, materials and devices
published pages: 87-104, ISSN: 2058-8437, DOI: 10.1038/s41578-019-0146-8
Nature Reviews Materials 5/2 2020-04-01
2018 Víctor García-López, João C. Waerenborgh, Bruno J. C. Vieira, Miguel Clemente-León, Eugenio Coronado
Iron( ii ) complexes of tris(2-pyridylmethyl)amine (TPMA) and neutral bidentate ligands showing thermal- and photo-induced spin crossover
published pages: 9156-9163, ISSN: 1477-9226, DOI: 10.1039/c8dt01425f
Dalton Transactions 47/27 2020-04-01
2018 Víctor Rubio‐Giménez, Neyvis Almora‐Barrios, Garin Escorcia‐Ariza, Marta Galbiati, Michele Sessolo, Sergio Tatay, Carlos Martí‐Gastaldo
Origin of the Chemiresistive Response of Ultrathin Films of Conductive Metal–Organic Frameworks
published pages: 15086-15090, ISSN: 1433-7851, DOI: 10.1002/anie.201808242
Angewandte Chemie International Edition 57/46 2020-04-01
2018 Michele Mattera, Víctor Rubio-Giménez, Sophie Delprat, Richard Mattana, Pierre Seneor, Sergio Tatay, Alicia Forment-Aliaga, Eugenio Coronado
Spontaneous growth of 2D coordination polymers on functionalized ferromagnetic surfaces
published pages: 8819-8828, ISSN: 2041-6520, DOI: 10.1039/c8sc03067g
Chemical Science 9/47 2020-04-01
2018 Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Miguel Clemente-León, Eugenio Coronado
Spin-crossover compounds based on iron( ii ) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic acid
published pages: 16958-16968, ISSN: 1477-9226, DOI: 10.1039/c8dt03511c
Dalton Transactions 47/47 2020-04-01
2020 Alvaro Seijas‐Da Silva, Roger Sanchis‐Gual, Jose A. Carrasco, Víctor Oestreicher, Gonzalo Abellán, Eugenio Coronado
Boosting the Supercapacitive Behavior of CoAl Layered Double Hydroxides via Tuning the Metal Composition and Interlayer Space
published pages: , ISSN: 2566-6223, DOI: 10.1002/batt.201900223
Batteries & Supercaps 2020-04-01
2019 J. de Bruijckere, P. Gehring, M. Palacios-Corella, M. Clemente-León, E. Coronado, J. Paaske, P. Hedegård, H. S. J. van der Zant
Ground-State Spin Blockade in a Single-Molecule Junction
published pages: , ISSN: 0031-9007, DOI: 10.1103/physrevlett.122.197701
Physical Review Letters 122/19 2020-04-01
2020 Marc Morant-Giner, Isaac Brotons, Nikita Y Shmelev, Artem L Gushchin, Luke Norman, Andrei N Khlobystov, Antonio Alberola, Sergio Tatay, Josep Canet-Ferrer, Alicia Forment-Aliaga, Eugenio Coronado
WS2/MoS2 heterostructures via thermal treatment of MoS2 layers electrostatically functionalized with W3S4 molecular clusters
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.202000248
Chemistry – A European Journal 2020-04-01
2019 Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado
Heteroleptic Iron(II) Spin-Crossover Complexes Based on a 2,6-Bis(pyrazol-1-yl)pyridine-type Ligand Functionalized with a Carboxylic Acid
published pages: 12199-12208, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.9b01526
Inorganic Chemistry 58/18 2020-04-01
2019 Jose A. Carrasco, Andrew Harvey, Damien Hanlon, Vicent Lloret, Dave McAteer, Roger Sanchis-Gual, Andreas Hirsch, Frank Hauke, Gonzalo Abellán, Jonathan N. Coleman, Eugenio Coronado
Liquid phase exfoliation of carbonate-intercalated layered double hydroxides
published pages: 3315-3318, ISSN: 1359-7345, DOI: 10.1039/c9cc00197b
Chemical Communications 55/23 2020-04-01
2019 Luis Escalera-Moreno, Alejandro Gaita-Ariño, Eugenio Coronado
Decoherence from dipolar interspin interactions in molecular spin qubits
published pages: , ISSN: 2469-9950, DOI: 10.1103/physrevb.100.064405
Physical Review B 100/6 2020-04-01

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