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Star Polymers SIGNED

When Soft Matter Goes Really Soft – A New Paradigm for Star Polymer Self-Assembly

Total Cost €

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EC-Contrib. €

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Partnership

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 Star Polymers project word cloud

Explore the words cloud of the Star Polymers project. It provides you a very rough idea of what is the project "Star Polymers" about.

reconfigurability    quasi    porous    linked    cores    grafted    located    lack    spontaneous    hard    freedom    flexible    absent    prevent    time    adverse    form    self    scattering    crystalline    fluctuations    stringent    blocks    structural    man    tools    segments    imprint    directional    building    uniformity    optimum    assemblies    resolved    separation    solvophilic    mechanical    envisioned    polymer    microscopy    assembly    propensity    polymers    class    patches    encountered    emergence    ordered    electron    limited    particle    periphery    drive    ing    introducing    virus    paradigm    comprise    supramolecular    prevents    arms    structures    metastable    analytic    trapped    complexity    undesired    guide    adaptability    deformability    made    capsids    flexibility    fail    reconfigure    macroscopic    orientations    multiprotein    micro    patchy    superstructure    locked    patch    equilibrium    lattices    simulation    biologic    synthetic    physical    criterion    solvophobic    pioneering    conformational    situ    geometric    place    relaxes    unprecedented    complementing    attached    background    block    colloidal    photonic    interactions    particles    core    complexes    soft    domains   

Project "Star Polymers" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITEIT EINDHOVEN 

Organization address
address: GROENE LOPER 3
city: EINDHOVEN
postcode: 5612 AE
website: www.tue.nl/en

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 175˙572 €
 EC max contribution 175˙572 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2018
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2020
 Duration (year-month-day) from 2020-01-13   to  2022-01-12

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITEIT EINDHOVEN NL (EINDHOVEN) coordinator 175˙572.00

Map

 Project objective

Biologic supramolecular assemblies, e.g., virus capsids and multiprotein complexes, show unprecedented complexity compared to man-made structures. A key feature of the building blocks facilitating the emergence of this structural complexity is their deformability. This enables them to reconfigure during assembly to find optimum orientations within the superstructure. Here, I propose to exploit the concept of reconfigurability as design criterion for developing a new class of colloidal building blocks. Where currently available hard particles fail to form macroscopic structures due to lack of building block uniformity and undesired metastable states encountered during assembly, introducing flexibility will prevent these adverse characteristics. The envisioned building blocks are based on polymer grafted cores, where the attached polymers arms comprise solvophilic and solvophobic blocks. The limited number of arms have significant conformational freedom, a feature absent in traditional hard particles. The solvophobic segments, located at the particle’s periphery, drive spontaneous polymer micro-phase separation into patchy domains which are then locked into place. These patches imprint directional interactions to guide self-assembly and are linked to the core via flexible solvophilic polymers, enabling patch fluctuations. The resulting patch adaptability prevents the system from getting trapped in non-equilibrium states and relaxes stringent requirements on geometric uniformity, promoting the formation of long-range ordered assemblies. Following simulation studies, these soft particles should have propensity to order into ‘open’ (quasi)crystalline lattices providing unique photonic, mechanical and porous characteristics. Complementing my physical/polymer synthetic background with pioneering analytic tools, e.g. time-resolved scattering and in situ electron microscopy, this project will detail a new paradigm for self-assembly and the importance of patch flexibility.

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The information about "STAR POLYMERS" are provided by the European Opendata Portal: CORDIS opendata.

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