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Star Polymers SIGNED

When Soft Matter Goes Really Soft – A New Paradigm for Star Polymer Self-Assembly

Total Cost €

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EC-Contrib. €

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Partnership

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 Star Polymers project word cloud

Explore the words cloud of the Star Polymers project. It provides you a very rough idea of what is the project "Star Polymers" about.

mechanical    resolved    optimum    arms    superstructure    polymers    block    flexibility    structural    scattering    segments    directional    building    supramolecular    deformability    lack    situ    paradigm    soft    reconfigurability    attached    drive    unprecedented    prevent    separation    limited    porous    hard    quasi    absent    locked    adaptability    crystalline    multiprotein    interactions    macroscopic    ing    structures    located    class    simulation    emergence    periphery    grafted    colloidal    propensity    patches    tools    comprise    geometric    imprint    blocks    criterion    freedom    virus    made    complexes    pioneering    place    orientations    biologic    solvophilic    envisioned    fail    particle    time    reconfigure    encountered    particles    stringent    introducing    background    domains    fluctuations    analytic    equilibrium    metastable    cores    lattices    assembly    flexible    trapped    prevents    electron    assemblies    physical    man    adverse    polymer    self    micro    complementing    solvophobic    core    patchy    patch    uniformity    conformational    synthetic    capsids    ordered    relaxes    linked    undesired    microscopy    spontaneous    form    guide    photonic    complexity   

Project "Star Polymers" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITEIT EINDHOVEN 

Organization address
address: GROENE LOPER 3
city: EINDHOVEN
postcode: 5612 AE
website: www.tue.nl/en

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 175˙572 €
 EC max contribution 175˙572 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2018
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2020
 Duration (year-month-day) from 2020-01-13   to  2022-01-12

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITEIT EINDHOVEN NL (EINDHOVEN) coordinator 175˙572.00

Map

 Project objective

Biologic supramolecular assemblies, e.g., virus capsids and multiprotein complexes, show unprecedented complexity compared to man-made structures. A key feature of the building blocks facilitating the emergence of this structural complexity is their deformability. This enables them to reconfigure during assembly to find optimum orientations within the superstructure. Here, I propose to exploit the concept of reconfigurability as design criterion for developing a new class of colloidal building blocks. Where currently available hard particles fail to form macroscopic structures due to lack of building block uniformity and undesired metastable states encountered during assembly, introducing flexibility will prevent these adverse characteristics. The envisioned building blocks are based on polymer grafted cores, where the attached polymers arms comprise solvophilic and solvophobic blocks. The limited number of arms have significant conformational freedom, a feature absent in traditional hard particles. The solvophobic segments, located at the particle’s periphery, drive spontaneous polymer micro-phase separation into patchy domains which are then locked into place. These patches imprint directional interactions to guide self-assembly and are linked to the core via flexible solvophilic polymers, enabling patch fluctuations. The resulting patch adaptability prevents the system from getting trapped in non-equilibrium states and relaxes stringent requirements on geometric uniformity, promoting the formation of long-range ordered assemblies. Following simulation studies, these soft particles should have propensity to order into ‘open’ (quasi)crystalline lattices providing unique photonic, mechanical and porous characteristics. Complementing my physical/polymer synthetic background with pioneering analytic tools, e.g. time-resolved scattering and in situ electron microscopy, this project will detail a new paradigm for self-assembly and the importance of patch flexibility.

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The information about "STAR POLYMERS" are provided by the European Opendata Portal: CORDIS opendata.

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lastchecktime (2021-10-17 3:37:19) correctly updated