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DYNAPORE SIGNED

Dynamic responsive porous crystals

Total Cost €

0

EC-Contrib. €

0

Partnership

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 DYNAPORE project word cloud

Explore the words cloud of the DYNAPORE project. It provides you a very rough idea of what is the project "DYNAPORE" about.

chemical    evaluation    organic    integrates    rigid    demonstrated    guide    solids    classes    inspired    structural    capability    crystallinity    functional    composition    intended    function    multidisciplinary    transform    guest    computation    organisation    protein    controls    environment    precision    flexibility    separation    property    dynamically    synergic    blocked    maximises    performance    dynamical    nature    reaction    reagent    harness    permits    structure    road    chemistry    proof    dynamic    crystalline    dynamics    inhibition    optimise    methodology    materials    accelerate    transferable    workflow    mimics    diffraction    linkers    made    frameworks    controllably    discovery    porosity    characterisation    develops    sorption    whilst    porous    restructuring    inorganic    man    flexible    metal    structures    efficiency    experimental    reorganising    selectivity    create    catalysis    builds    synthesis    prediction    computational    perform    restructure    atomic    cascade    guests    vision    relationship   

Project "DYNAPORE" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF LIVERPOOL 

Organization address
address: BROWNLOW HILL 765 FOUNDATION BUILDING
city: LIVERPOOL
postcode: L69 7ZX
website: www.liverpool.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 2˙493˙425 €
 EC max contribution 2˙493˙425 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2015-AdG
 Funding Scheme ERC-ADG
 Starting year 2016
 Duration (year-month-day) from 2016-10-01   to  2021-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF LIVERPOOL UK (LIVERPOOL) coordinator 2˙493˙425.00

Map

 Project objective

The project addresses the long-term vision of man-made materials with chemical selectivity and functional efficiency produced by dynamic structural flexibility. These materials are not intended as protein mimics; they are however inspired by nature’s use of flexible rather than rigid systems, with their ability to dynamically restructure around guests and thus perform highly specific chemistry. Such materials would transform chemical processes through their precision, for example by reorganising to accelerate each step of a cascade reaction without reagent or product inhibition. The road to this vision is blocked as we do not have the methodology and understanding to control such materials. The aim is to develop synergic, multidisciplinary experimental and computational capability to harness the dynamics of flexible crystalline porous solids for function, demonstrated in separation and catalysis. This will enable design and synthesis of materials that controllably adopt distinct structures according to their chemical environment to optimise performance. We will create a new workflow that integrates understanding of the structure-composition-dynamics-property relationship into the materials design and discovery process. This workflow builds on proof-of-concept in (i) chemical control of dynamical restructuring in flexible crystalline porous materials and in the use of dynamics to (ii) enhance function and (iii) guide synthesis. Crystalline flexible porous materials are selected because crystallinity maximises the atomic-scale understanding generated, which is transferable to other materials classes, whilst porosity permits sorption and organisation of guests that controls function. This inorganic materials chemistry project develops integrated capability in chemical synthesis (new metal-organic frameworks and linkers), computation (prediction and evaluation of structure and dynamical guest response), characterisation (e.g. by diffraction) and measurement of function.

 Publications

year authors and title journal last update
List of publications.
2019 Elliot J Carrington, Rémi Petuya, Rebecca K Hylton, Yong Yan, Dmytro Antypov, George Darling, Matthew Dyer, Neil G Berry, Alexandros P Katsoulidis, Matthew J Rosseinsky
A Highly Flexible Metal-Organic Framework Constructed from Asymmetric Flexible Linkers and Heptanuclear Zinc Carboxylate Secondary Building Units and its Anisotropic Dynamic Responses Exhibited During Guest Removal and Single Crystal Coordinated Solvent Exchange
published pages: , ISSN: 1528-7483, DOI: 10.26434/chemrxiv.8048321.v1
Crystal Growth & Design 2019-06-07
2019 Alexandros P. Katsoulidis, Dmytro Antypov, George F. S. Whitehead, Elliot J. Carrington, Dave J. Adams, Neil G. Berry, George R. Darling, Matthew S. Dyer, Matthew J. Rosseinsky
Chemical control of structure and guest uptake by a conformationally mobile porous material
published pages: 213-217, ISSN: 0028-0836, DOI: 10.1038/s41586-018-0820-9
Nature 565/7738 2019-06-06
2017 J. Haddad, G. F. S. Whitehead, A. P. Katsoulidis, M. J. Rosseinsky
In-MOFs based on amide functionalised flexible linkers
published pages: 327-335, ISSN: 1359-6640, DOI: 10.1039/c7fd00085e
Faraday Discussions 201 2019-06-06

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The information about "DYNAPORE" are provided by the European Opendata Portal: CORDIS opendata.

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