Explore the words cloud of the MOFcat project. It provides you a very rough idea of what is the project "MOFcat" about.
The following table provides information about the project.
|Coordinator Country||Sweden [SE]|
|Total cost||1˙968˙750 €|
|EC max contribution||1˙968˙750 € (100%)|
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
|Duration (year-month-day)||from 2017-01-01 to 2021-12-31|
Take a look of project's partnership.
|1||UPPSALA UNIVERSITET||SE (UPPSALA)||coordinator||1˙968˙750.00|
Organometallic redox-catalysts of energy relevance, i.e. water and hydrogen oxidation, and proton and carbon dioxide reduction catalysts, will be incorporated into metal-organic frameworks (MOFs). Immobilization and spatial organization of the molecular catalysts will stabilize their molecular integrity and ensure longevity and recyclability of the resulting MOFcats. The organized environment provided by the MOF will enable the control of conformational flexibility, diffusion, charge transport, and higher coordination sphere effects that play crucial roles in enzymes, but cannot be addressed in homogenous solution and are thus largely unexplored. The effect that the MOF environment has on catalysis will be directly probed electrochemically in MOFcats that are immobilized or grown on electrode surfaces. In combination with spectroscopic techniques in spectroelectrochemical cells, intermediates in the catalytic cycles will be detected and characterized. Kinetic information of the individual steps in the catalytic cycles will be obtained in MOFs that contain both a molecular photosensitizer (PS) and a molecular catalyst (PS-MOFcats). The envisaged systems will allow light-induced electron transfer processes to generate reduced or oxidized catalyst states the reactivity of which will be studied with high time resolution by transient UV/Vis and IR spectroscopy. The acquired fundamental mechanistic knowledge is far beyond the current state-of-the-art in MOF chemistry and catalysis, and will be used to prepare MOFcat-based electrodes that function at highest possible rates and lowest overpotentials. PS-MOFcats will be grown on flat semiconductor surfaces, and explored as a novel concept to photoanode and -cathode designs for dye-sensitized solar fuel devices (DSSFDs). The design is particularly appealing as it accommodates high PS concentrations for efficient light-harvesting, while providing potent catalysts close to the solvent interface.
|year||authors and title||journal||last update|
Brian D. McCarthy, Timofey Liseev, Anna M. Beiler, Kelly L. Materna, Sascha Ott
Facile Orientational Control of M 2 L 2 P SURMOFs on âŸ¨100âŸ© Silicon Substrates and Growth Mechanism Insights for Defective MOFs
published pages: 38294-38302, ISSN: 1944-8244, DOI: 10.1021/acsami.9b12407
|ACS Applied Materials & Interfaces 11/41||2020-01-14|
Souvik Roy, Zhehao Huang, Asamanjoy Bhunia, Ashleigh Castner, Arvind K. Gupta, Xiaodong Zou, Sascha Ott
Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metalâ€“Organic Framework Thin Film
published pages: 15942-15950, ISSN: 0002-7863, DOI: 10.1021/jacs.9b07084
|Journal of the American Chemical Society 141/40||2020-01-14|
Ulrike Fluch, Brian D. McCarthy, Sascha Ott
Post synthetic exchange enables orthogonal click chemistry in a metal organic framework
published pages: 45-49, ISSN: 1477-9226, DOI: 10.1039/c8dt04563a
|Dalton Transactions 48/1||2019-08-29|
Ben A. Johnson, Asamanjoy Bhunia, Sascha Ott
Electrocatalytic water oxidation by a molecular catalyst incorporated into a metalâ€“organic framework thin film
published pages: 1382-1388, ISSN: 1477-9226, DOI: 10.1039/c6dt03718f
|Dalton Transactions 46/5||2019-06-18|
Asamanjoy Bhunia, Ben A. Johnson, Joanna Czapla-Masztafiak, Jacinto SÃ¡, Sascha Ott
Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration
published pages: 7770-7773, ISSN: 1359-7345, DOI: 10.1039/c8cc02300j
|Chemical Communications 54/56||2019-06-18|
Sonja Pullen, Souvik Roy, Sascha Ott
[FeFe] Hydrogenase active site model chemistry in a UiO-66 metalâ€“organic framework
published pages: 5227-5230, ISSN: 1359-7345, DOI: 10.1039/c7cc01620d
|Chemical Communications 53/37||2019-06-18|
Ben A. Johnson, Asamanjoy Bhunia, Honghan Fei, Seth M. Cohen, Sascha Ott
Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers
published pages: 2985-2994, ISSN: 0002-7863, DOI: 10.1021/jacs.7b13077
|Journal of the American Chemical Society 140/8||2019-06-18|
Edgar Mijangos, Souvik Roy, Sonja Pullen, Reiner Lomoth, Sascha Ott
Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metalâ€“organic frameworks
published pages: 4907-4911, ISSN: 1477-9226, DOI: 10.1039/c7dt00578d
|Dalton Transactions 46/15||2019-06-18|
Souvik Roy, Asamanjoy Bhunia, Nils Schuth, Michael Haumann, Sascha Ott
Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metalâ€“organic framework
published pages: 1148-1152, ISSN: 2398-4902, DOI: 10.1039/c8se00072g
|Sustainable Energy & Fuels 2/6||2019-06-18|
Ulrike Fluch, Valentina Paneta, Daniel Primetzhofer, Sascha Ott
Uniform distribution of post-synthetic linker exchange in metalâ€“organic frameworks revealed by Rutherford backscattering spectrometry
published pages: 6516-6519, ISSN: 1359-7345, DOI: 10.1039/c7cc02631e
|Chemical Communications 53/48||2019-06-18|
Souvik Roy, Vlad Pascanu, Sonja Pullen, Greco GonzÃ¡lez Miera, BelÃ©n MartÃn-Matute, Sascha Ott
Catalyst accessibility to chemical reductants in metalâ€“organic frameworks
published pages: 3257-3260, ISSN: 1359-7345, DOI: 10.1039/c7cc00022g
|Chemical Communications 53/22||2019-06-18|
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