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CO2Polymerisation SIGNED

Conversion of CO2/H2O to Polyethylene through Cascade Electro-reduction–Polymerisation Catalysis

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 CO2Polymerisation project word cloud

Explore the words cloud of the CO2Polymerisation project. It provides you a very rough idea of what is the project "CO2Polymerisation" about.

catalysis    converting    multiscale    direct    electrochemical    feedstocks    fuels    candidates    separately    simultaneous    conversion    novelty    responsible    mass    cu    carry    co2    quantum    conversions    achievements    model    ethylene    predict    ziegler    demonstrated    global    constituents    binding    software    time    cascade    copper    constructing    co    intermediates    sequentially    continuum    tones    manifold    dynamics    species    highlighted    environmental    chemical    energy    catalysts    million    reaction    carbon    transforms    experimentally    polymerization    packages    valuable    water    multiphysics    catalyst    dioxide    hydrocarbon    electro    feedstock    presented    computational    hydrogenation    metallocene    polyethylene    transport    c2h4    catalytic    palladium    electrolyte    indirect    occurs    executed    enticing    transformation    parallel    annually    bifunctional    abundant    pd    creative    settling    warming    microkinetic   

Project "CO2Polymerisation" data sheet

The following table provides information about the project.

Coordinator
KEMIJSKI INSTITUT 

Organization address
address: HAJDRIHOVA 19
city: LJUBLJANA
postcode: 1000
website: http://www.ki.si

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Slovenia [SI]
 Total cost 162˙040 €
 EC max contribution 162˙040 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2019
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2020
 Duration (year-month-day) from 2020-09-01   to  2022-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    KEMIJSKI INSTITUT SI (LJUBLJANA) coordinator 162˙040.00

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 Project objective

The global production of polyethylene is over 100 million tones annually. Carbon dioxide is a major cause of global warming but at the same time, it is also an abundant feedstock for hydrocarbon energy fuels. Electrochemical reduction of CO2 into valuable chemical feedstocks such as polyethylene is a highly enticing challenge for simultaneous settling of energy and environmental issues. Currently, CO2 conversion to polyethylene occurs through an indirect two-step process including CO2 catalytic conversions to ethylene (CO2 hydrogenation) and ethylene to polyethylene (ethylene polymerization) using two different catalysts, separately. The novelty of my research is constructing a bifunctional catalyst for CO2 direct conversion to polyethylene through a cascade of electro-reduction–polymerization catalysis in the presence of water. So far, a catalyst that sequentially transforms CO2 into polyethylene has not yet been presented. Manifold catalysts have been demonstrated as potential candidates for CO2 polymerization to polyethylene. The state-of-the-art catalysts as constituents of the proposed bifunctional catalyst would be Copper and Palladium. Cu is responsible for binding *CO intermediates and converting them into C2H4 and Pd is highlighted for ethylene polymerization after Ziegler-type and metallocene-type catalysts. Using computational software packages, I will develop a multiscale and multiphysics model of direct CO2 electrochemical reduction to polyethylene over Cu-Pd bifunctional catalyst to predict the intermediates and products. To achieve this goal, I will carry out a quantum chemical analysis of the reaction pathway, a microkinetic model of the reaction dynamics, and a continuum model for mass transport of all species through the electrolyte. In parallel, computational achievements will be executed experimentally to produce a creative bifunctional catalyst from merging two different catalysts for the CO2 cascade transformation to polyethylene directly.

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The information about "CO2POLYMERISATION" are provided by the European Opendata Portal: CORDIS opendata.

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