Explore the words cloud of the ATMCinsituNMR project. It provides you a very rough idea of what is the project "ATMCinsituNMR" about.
The following table provides information about the project.
THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE
|Coordinator Country||United Kingdom [UK]|
|Total cost||183˙454 €|
|EC max contribution||183˙454 € (100%)|
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
|Duration (year-month-day)||from 2015-03-01 to 2017-02-28|
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|1||THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE||UK (CAMBRIDGE)||coordinator||183˙454.00|
Concerns about finite energy resources and the need to decrease greenhouse gas emissions have increased the use of intermittent renewable energies on the electric grid. This is not without its challenges requiring more efficient ways to store electrical energy to balance demand with supply. Li-ion batteries (LIBs) are the most desirable form of energy storage (high energy / power densities) but an increasing demand of Li commodity chemicals combined with geographically-constrained reserves will drive up prices in the future. Due to the high abundance, low costs and very suitable redox potential, Na-ion batteries (NIBs) should open new avenues of research and engineering as complementary alternatives to LIBs. This shift has to be accompanied with a deeper understanding of the chemical reactions involving the multiple cell components. The proposed project focuses on a next step of in situ NMR spectroscopy, offering the unique possibility of non-invasive real-time studies of batteries under operating conditions – to track the formation of intermediate phases and investigate electrolyte decomposition during cycling of LIBs and NIBs. Significantly different shifts of the multi-component samples, resonance broadening as well as interferences of the NMR and external battery cycler (EBC) circuit impair the experiments. Hence, we will set up a novel NMR probe system allowing “on-the-fly” adjustment of the NMR circuit during the measurement and sample orientation changes via an automated goniometer. Moreover, an entirely new NMR-EBC-connection design will benefit the real-time experiments. This next level Automatic Tuning Matching Cycler (plus Goniometer) – ATMC(G) – in situ NMR approach will be established in a comparative study on lithium vs. sodium iron phosphate cathodes in LIBs and NIBs, respectively, including the application of new electrolytes to improve battery safety and cost factors. The application to a wider range of systems will include Na-Sn anodes for NIBs.
|year||authors and title||journal||last update|
Yue Deng, Christopher Eames, Jean-NoÃ«l Chotard, Fabien LalÃ¨re, Vincent Seznec, Steffen Emge, Oliver Pecher, Clare P. Grey, Christian Masquelier, M. Saiful Islam
Structural and Mechanistic Insights into Fast Lithium-Ion Conduction in Li 4 SiO 4 â€“Li 3 PO 4 Solid Electrolytes
published pages: 9136-9145, ISSN: 0002-7863, DOI: 10.1021/jacs.5b04444
|Journal of the American Chemical Society 137/28||2019-07-23|
Oliver Pecher, Anastasia Vyalikh, Clare P. Grey
Challenges and new opportunities of in situ NMR characterization of electrochemical processes
published pages: 20011, ISSN: , DOI: 10.1063/1.4961903
|AIP Conference Proceedings volume 1765||2019-07-23|
Lavinia M. Scherf, Antti J. Karttunen, Oliver Pecher, Pieter C. M. M. Magusin, Clare P. Grey, Thomas F. FÃ¤ssler
[Ge 2 ] 4âˆ’ Dumbbells with Very Short Geâˆ’Ge Distances in the Zintl Phase Li 3 NaGe 2 : A Solid-State Equivalent to Molecular O 2
published pages: 1075-1079, ISSN: 1433-7851, DOI: 10.1002/anie.201508044
|Angewandte Chemie International Edition 55/3||2019-07-23|
Lavinia M. Scherf, Oliver Pecher, Kent J. Griffith, Frank Haarmann, Clare P. Grey, Thomas F. FÃ¤ssler
Zintl Phases K 4- x Na x Si 4 (1 â‰¤ x â‰¤ 2.2) and K 7 NaSi 8 : Synthesis, Crystal Structures, and Solid-State NMR Spectroscopic Investigations
published pages: 4674-4682, ISSN: 1434-1948, DOI: 10.1002/ejic.201600735
|European Journal of Inorganic Chemistry 2016/28||2019-07-23|
Oliver Pecher, David M. Halat, Jeongjae Lee, Zigeng Liu, Kent J. Griffith, Marco Braun, Clare P. Grey
Enhanced efficiency of solid-state NMR investigations of energy materials using an external automatic tuning/matching (eATM) robot
published pages: 127-136, ISSN: 1090-7807, DOI: 10.1016/j.jmr.2016.12.008
|Journal of Magnetic Resonance 275||2019-07-23|
Oliver Pecher, Javier Carretero-GonzÃ¡lez, Kent J. Griffith, Clare P. Grey
Materialsâ€™ Methods: NMR in Battery Research
published pages: 213-242, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b03183
|Chemistry of Materials 29/1||2019-07-23|
Oliver Pecher, Paul M. Bayley, Hao Liu, Zigeng Liu, Nicole M. Trease, Clare P. Grey
Automatic Tuning Matching Cycler (ATMC) in situ NMR spectroscopy as a novel approach for real-time investigations of Li- and Na-ion batteries
published pages: 200-209, ISSN: 1090-7807, DOI: 10.1016/j.jmr.2016.02.008
|Journal of Magnetic Resonance 265||2019-07-23|
Joshua M. Stratford, Phoebe K. Allan, Oliver Pecher, Philip A. Chater, Clare P. Grey
Mechanistic insights into sodium storage in hard carbon anodes using local structure probes
published pages: 12430-12433, ISSN: 1359-7345, DOI: 10.1039/C6CC06990H
|Chem. Commun. 52/84||2019-07-23|
Gosuke Oyama, Oliver Pecher, Kent J. Griffith, Shin-ichi Nishimura, Roberta Pigliapochi, Clare P. Grey, Atsuo Yamada
Sodium Intercalation Mechanism of 3.8 V Class Alluaudite Sodium Iron Sulfate
published pages: 5321-5328, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b01091
|Chemistry of Materials 28/15||2019-07-23|
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